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Cyclic phosphorochloridites (chloridates) based on chiral butane-2,3-diol and dihydrobenzoin as reagents for the analysis of enantiomeric compositions of alcohols by31P NMR spectroscopy

  • Physical Chemistry
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Abstract

The use of cyclic phosphorochloridites which were prepared based on PCl3 and chiral butane-2,3-diol or hydrobenzoin as possible reagents for the analysis of the enantiomeric composition of chiral alcohols by31P NMR spectroscopy is considered. The diastereomeric dispersion of chemical shifts of the resulting phosphites as well as of derived phosphates and thiophosphates is compared with that of structurally similar reagents.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420083, Kazan, Russian Federation

    A. A. Bredikhin, Z. A. Bredikhina, L. M. Gaisina, E. I. Strunskaya & N. M. Azancheev

Authors
  1. A. A. Bredikhin
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  2. Z. A. Bredikhina
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  3. L. M. Gaisina
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  4. E. I. Strunskaya
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  5. N. M. Azancheev
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 308–311, February, 2000.

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Bredikhin, A.A., Bredikhina, Z.A., Gaisina, L.M. et al. Cyclic phosphorochloridites (chloridates) based on chiral butane-2,3-diol and dihydrobenzoin as reagents for the analysis of enantiomeric compositions of alcohols by31P NMR spectroscopy. Russ Chem Bull 49, 310–313 (2000). https://doi.org/10.1007/BF02494678

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  • DOI: https://doi.org/10.1007/BF02494678

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