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IR study of ion-molecular interactions in the system methanesulfonic acid-ethyl acetate

  • Physical Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

The complex formation in the methanesulfonic acid (MSA)—ethyl acetate (EA) system was studied by Multiple Attenuated Total Reflection (MATR) IR spectroscopy at 30°C. In solutions with excess EA, neither protonation of a base nor formation of complexes with a strong symmetrical H bond was observed. Molecular complexes EA·MSA are found in these solutions. Complexes formed by the strong symmetric H bond are observed in the system when the MSA content exceeds 50 mol.%

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Authors and Affiliations

  1. N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 117977, Moscow, Russian Federation

    V. V. Burdin, V. D. Maiorov & N. B. Librovich

Authors
  1. V. V. Burdin
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  2. V. D. Maiorov
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  3. N. B. Librovich
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2. pp. 292–294, February, 2000.

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Burdin, V.V., Maiorov, V.D. & Librovich, N.B. IR study of ion-molecular interactions in the system methanesulfonic acid-ethyl acetate. Russ Chem Bull 49, 295–297 (2000). https://doi.org/10.1007/BF02494675

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  • DOI: https://doi.org/10.1007/BF02494675

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