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IR Spectroscopy of Solutions of Dimethylsulfoxide in Monoethanolamine

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Abstract

Solutions of dimethylsulfoxide (DMSO) in monoethanolamine (MEA) are studied via IR spectroscopy on a Bruker Tensor 37 FT-IR spectrometer in the wavenumber range of 900–4000 cm−1. The concentrations of DMSO are 2–66 mol %. The region of the stretching vibrations of hydrogen-bonded OH and NH2 groups (2800–4000 cm−1) and the region of the S=O vibrations of DMSO (900–1100 cm−1) are studied in detail. The obtained data are compared to the IR spectra of solutions of DMSO in ethylene glycol in the regions of OH and S=O stretching vibrations. The effect the NH2 group in the MEA molecule has on the interaction in the DMSO–MEA system and the physicochemical properties of this system as compared to ethylene glycol solutions of DMSO are discussed.

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REFERENCES

  1. D. H. Rassmunsen and A. P. Mackenzie, Nature (London, U.K.) 220, 1315 (1968).

    Article  Google Scholar 

  2. A. Baudot, M. L. Cacela, M. L. Duarte, and R. Fausto, Criobiology 44, 150 (2002).

    Article  CAS  Google Scholar 

  3. M. N. Rodnikova, Doctoral (Chem.) Dissertation (Moscow, 1998).

  4. Q. F. Ahkong, D. Fischer, W. Tompion, and J. A. Lucy, Nature (London, U.K.) 253, 194 (1975).

    Article  CAS  Google Scholar 

  5. J. E. Lovelock and M. W. Y. Bishop, Nature (London, U.K.) 183, 1394 (1959).

    Article  CAS  Google Scholar 

  6. T. J. Anchordoguy, C. A. Ceccini, J. N. Crowe, and L. M. Crowe, Cryobiology 28, 467 (1991).

    Article  CAS  Google Scholar 

  7. H. Fader, H. D. Dreizer, V. Rudolph, and Z. Typke, Z. Naturforsch. 244, 266 (1969).

  8. F. Reza and S. Mohammad, Iran. Chem. Commun. 2, 244 (2014).

    Google Scholar 

  9. Yu. V. Novakovskaya and M. N. Rodnikova, Struct. Chem. 26, 177 (2015).

    Article  CAS  Google Scholar 

  10. Yu. V. Novakovskaya and M. N. Rodnikova, Russ. J. Inorg. Chem. 59, 1290 (2014).

    Article  CAS  Google Scholar 

  11. M. N. Rodnikova, Zh. Fiz. Khim. 67, 275 (1993).

    CAS  Google Scholar 

  12. I. A. Solonina, M. N. Rodnikova, M. R. Kiselev, A. V. Khoroshilov, and S. V. Makaev, Russ. J. Inorg. Chem. 64, 1054 (2019).

    Article  CAS  Google Scholar 

  13. Yu. Yu. Lur’e, Handbook of Analytical Chemistry (Khimiya, Moscow, 1979) [in Russian].

    Google Scholar 

  14. Yu. Ya. Kharitonov, E. G. Khoshabova, M. N. Rodnikova, et al., Dokl. Akad. Nauk SSSR 304, 917 (1989).

    CAS  Google Scholar 

  15. I. A. Solonina, M. N. Rodnikova, M. R. Kiselev, and A. V. Khoroshilov, Russ. J. Phys. Chem. A 89, 910 (2015).

    Article  CAS  Google Scholar 

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Funding

This work was performed as a part of a State Task for the Kurnakov Institute of General and Inorganic Chemistry in the field of fundamental research. It was supported by the Russian Foundation for Basic Research, project no. 19-03-00215.

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Authors and Affiliations

  1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 199991, Moscow, Russia

    E. G. Kononova

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    M. N. Rodnikova, I. A. Solonina & E. V. Shirokova

Authors
  1. E. G. Kononova
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  2. M. N. Rodnikova
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  3. I. A. Solonina
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  4. E. V. Shirokova
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Corresponding author

Correspondence to M. N. Rodnikova.

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Translated by K. Utegenov

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Kononova, E.G., Rodnikova, M.N., Solonina, I.A. et al. IR Spectroscopy of Solutions of Dimethylsulfoxide in Monoethanolamine. Russ. J. Phys. Chem. 94, 2233–2237 (2020). https://doi.org/10.1134/S0036024420110151

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  • DOI: https://doi.org/10.1134/S0036024420110151

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