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Cubane derivatives

5. Synthesis of 1-bromo-9,9-ethylenedioxypentacyclo[4.3.0.02,5.03,8.04,7]non-4-ylcarbinol

  • Organic Chemistry
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Abstract

The reduction of 1-bromo-9,9-ethylenedioxypentacyclo[4.3.0.02,5.03,8.04,7]nonane-4-carboxylic acid (2) with lithium aluminum hydride and aluminum hydride in THF was studied. A new effective method for preparing 1-bromo-9,9-ethylenedioxypentacyclo[4.3.0.02,5.03,8.04,7]-non-4-ylcarbinol (1) based on reduction of2 with AlH3 under mild conditions was developed.

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Authors and Affiliations

  1. Institute for Chemical Physics Research in Chernogolovka, Russian Academy of Sciences, 142432, Chermogolovka, Moscow Region, Russian Federation

    V. V. Zakharov, G. P. Bugaeva, N. Yu. Andreeva, L. B. Romanova & L. T. Eremenko

Authors
  1. V. V. Zakharov
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  2. G. P. Bugaeva
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  3. N. Yu. Andreeva
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  4. L. B. Romanova
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  5. L. T. Eremenko
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Additional information

For Part 4, see Ref. 1.

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2296–2299, November, 1998.

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Zakharov, V.V., Bugaeva, G.P., Andreeva, N.Y. et al. Cubane derivatives. Russ Chem Bull 47, 2226–2228 (1998). https://doi.org/10.1007/BF02494286

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  • DOI: https://doi.org/10.1007/BF02494286

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