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Nucleophilic Addition of Polyfunctional Amines to Acetonitrile Derivatives of closo-Borate Anions [BnHn – 1NCCH3]– (n = 10, 12)

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Abstract

Methods for the preparation of new amidine-closo-borates based on the processes of nucleophilic addition of bifunctional amines containing free functional groups –NH2, –SH to nitrile derivatives of the closo-decaborate and closo-dodecaborate anions have been developed. These derivatives can potentially act as agents for 10B-NCT and serve as starting compounds for further preparation of borylated derivatives by organic chemistry methods. The structures of the obtained compounds have been confirmed by 1H, 11B, 13C NMR spectroscopies and ESI mass spectroscopy.

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ACKNOWLEDGMENTS

The work was performed using the equipment of the Center for Collective Use of the Physical Methods of Investigation of the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Science, which operates with the support of the State Assignment of the Kurnakov Institute RAS in the field of fundamental scientific research.

Funding

The work was supported by the Russian Science Foundation (grant no. 21-73-10292).

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    A. V. Nelyubin, N. A. Selivanov, A. Yu. Bykov, I. N. Klyukin, A. P. Zhdanov, K. Yu. Zhizhin & N. T. Kuznetsov

  2. MIREA—Russian Technological University, 119571, Moscow, Russia

    M. S. Sokolov

Authors
  1. A. V. Nelyubin
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  2. M. S. Sokolov
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  3. N. A. Selivanov
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  5. I. N. Klyukin
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  6. A. P. Zhdanov
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  8. N. T. Kuznetsov
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Correspondence to A. P. Zhdanov.

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Translated by V. Avdeeva

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Nelyubin, A.V., Sokolov, M.S., Selivanov, N.A. et al. Nucleophilic Addition of Polyfunctional Amines to Acetonitrile Derivatives of closo-Borate Anions [BnHn – 1NCCH3]– (n = 10, 12). Russ. J. Inorg. Chem. 67, 1751–1755 (2022). https://doi.org/10.1134/S003602362260109X

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