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Comparison of high-performance liquid chromatography — Mass spectroscopy and capillary electrophoresis— mass spectroscopy for the analysis of phenolic compounds in diethyl ether extracts of red wines

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Summary

Reversed-phase high-performance liquid chromatography-mass spectroscopy (HPLC-MS) and capillary electrophoresis-mass spectroscopy (CE-MS) have been compared for the analysis of phenolic compounds in diethyl ether extracts of red wines. MS was performed in the electrospray negative-ionization mode. Despite the much higher separation efficiency of CE compared with LC, LC-MS furnishes far superior information for elucidation of the structure of the constituents. LC-MS enabled the identification of twenty-four compounds whereas only thirteen were characterized by CE-MS.

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Authors and Affiliations

  1. Ghent University, Department of Organic Chemistry, Laboratory of Separation Sciences, Krijgslaan 281 (S4), 9000, Ghent, Belgium

    G. Vanhoenacker & P. Sandra

  2. Faculty of Pharmaceutical Sciences, Laboratory of Pharmacognosy and Phytochemistry, Ghent University, Harelbekestraat 72, 9000, Ghent, Belgium

    G. Vanhoenacker & D. De Keukeleire

  3. Department of Chemistry, CENSSUS, University of Stellenbosch, Private Bag X1, 7602, Matieland, South Africa

    A. De Villiers & P. Sandra

  4. Janssen Pharmaceutica, Lammerdries 55, 2250, Olen, Belgium

    K. Lazou

Authors
  1. G. Vanhoenacker
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  2. A. De Villiers
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  3. K. Lazou
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  4. D. De Keukeleire
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  5. P. Sandra
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Vanhoenacker, G., De Villiers, A., Lazou, K. et al. Comparison of high-performance liquid chromatography — Mass spectroscopy and capillary electrophoresis— mass spectroscopy for the analysis of phenolic compounds in diethyl ether extracts of red wines. Chromatographia 54, 309–315 (2001). https://doi.org/10.1007/BF02492675

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  • DOI: https://doi.org/10.1007/BF02492675

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