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Behaviour of Prussian Blue during its interaction with ozone

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Abstract

The interaction of ozone with Prussian Blue has been studied by Mössbauer, infrared and XRD techniques. All spectral results reveal a reversible conversion of ferrocyanide to ferricyanide with preservation of the crystal skeleton. Ferric ferricyanide obtained by ozonization of ferric ferrocyanide has Mössbauer parameters different to those of an ordered Prussian Brown, which has been attributed to secondary reaction products located at the zeolite voids of the former compound.

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Authors and Affiliations

  1. Centro Nacional de Investigaciones Cientificas, P.O. Box 6990, Havana, Cuba

    E. Reguera, J. Fernández-Bertrán, C. Díaz & J. Molerio

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  1. E. Reguera
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  2. J. Fernández-Bertrán
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  3. C. Díaz
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  4. J. Molerio
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Reguera, E., Fernández-Bertrán, J., Díaz, C. et al. Behaviour of Prussian Blue during its interaction with ozone. Hyperfine Interact 73, 285–294 (1992). https://doi.org/10.1007/BF02418603

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  • DOI: https://doi.org/10.1007/BF02418603

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