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Kinetics of the N oxidation of some compounds of the pyridine series with perbenzoic acid in chloroform and aqueous dioxane

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

A comparative study of the kinetics of the N oxidation of 19 derivatives of the pyridine series with perbenzoic acid in chloroform and aqueous dioxane at 20, 25, 30, and 35 °C was made. The rate constants, the parameters of the Arrhenius equation, and the activation energies of the N oxidation of the indicated monoazines were determined. The scale of the reactivities of the derivatives of the pyridine series was calculated within the framework of the Pearson hard-soft acid-base concept.

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Authors and Affiliations

  1. K. L. Khetagurov North Ossetian State University, 362021, Ordzhonikidze

    R. E. Lokhov

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  1. R. E. Lokhov
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 354–362, March, 1980.

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Lokhov, R.E. Kinetics of the N oxidation of some compounds of the pyridine series with perbenzoic acid in chloroform and aqueous dioxane. Chem Heterocycl Compd 16, 264–271 (1980). https://doi.org/10.1007/BF02401724

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  • DOI: https://doi.org/10.1007/BF02401724

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