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New polymer coated anion-exchange HPLC-phases: Immobilization of poly (2-hydroxy, 3N-ethylenediamino) butadiene on silica and alumina

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Summary

PHEB=POLY(2-hydroxy, 3N-ethylenediamino)butadiene has been synthesized. This unsaturated pre-polymer can be immobilized on different, preferably inorganic supports of suitable porosity such as silica or alumina by cross-linking. Weak anion-exchange phase are obtained. Such phases do not have the disadvantages of organic polymeric phases, regarding pressure stability and swelling by solvent influence. The ion-exchange capacity and the retentivity of IE-separations can deliberately be varied via the thickness of the cross-linked polymer layer. Alumina can also be coated with PHEB applying the same cross-linking procedure. Such phases exhibit an exceptional chemical stability even when operated with mobile phases at very high pH-values. Separations of excellent selectivity are achieved for inorganic anions, as well as with mixtures of aliphatic and aromatic free acids also including hydroxy- (mono- or poly)carboxylic acids.

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Author notes

  1. J. Köhler

    Present address: Pflanzenschutzzentrum Monheim, Bayer AG, B.6610, 5090, Leverkusen, Bayerwerk

Authors and Affiliations

  1. Chromatography Department, Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-4330, Mühlheim/Ruhr, FRG

    G. Heinemann, J. Köhler & G. Schomburg

Authors
  1. G. Heinemann
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  2. J. Köhler
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  3. G. Schomburg
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Heinemann, G., Köhler, J. & Schomburg, G. New polymer coated anion-exchange HPLC-phases: Immobilization of poly (2-hydroxy, 3N-ethylenediamino) butadiene on silica and alumina. Chromatographia 23, 435–441 (1987). https://doi.org/10.1007/BF02311821

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  • DOI: https://doi.org/10.1007/BF02311821

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