Skip to main content
SpringerLink
Log in

A novel covalently modified aminated silica-based anion exchanger for ion chromatography

  • Published:
Moscow University Chemistry Bulletin Aims and scope

Abstract

A novel method for the synthesis of anion exchangers for ion chromatography that provides the covalent attachment and spatial movement of the ion-exchange layer away from the silica surface is proposed. The new approach includes the following steps: alkylation of aminated silica with 1,4-butanediol diglycidyl ether and then amination using polyethyleneimine. The obtained anion exchanger allows the simultaneous separation of 11 anions (C2H5COO−, CH3COO−, HCOO−, BrO −3 , Cl−,NO −2 Br−, NO −3 I−, SCN−, ClO −4 ) in 18 minutes and demonstrates good efficiency (up to 62,000 TP/m for I-) in the single column ion chromatography mode with indirect UV-detection using potassium hydrogen phthalate as an eluent.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Pirogov, A.V., J. Anal. Chem., 2000, vol. 55, no. 12, p. 1155.

    Article  CAS  Google Scholar 

  2. Pirogov, A.V., Svintsova, N.V., Kuzina, O.V., Krokhin, O.V., Platonov, M.M., and Shpigun, O.A., Fresenius J. Anal. Chem., 1998, vol. 361, p. 288.

    Article  CAS  Google Scholar 

  3. Pirogov, A.V., Platonov, M.M., and Shpigun, O.A., J. Chromatogr. A, 1999, vol. 850, p. 53.

    Article  CAS  Google Scholar 

  4. Krokhin, O.V., Pirogov, A.V., and Shpigun, O.A., J. Anal. Chem., 2002, vol. 57, no. 10, p. 920.

    Article  CAS  Google Scholar 

  5. Pirogov, A.V., Svintsova, N.V., Kuzina, O.V., Krokhin, O.V., and Shpigun, O.A., Vestn. Mosk. Univ., Ser. 2: Khim., 2000, vol. 41, no. 4, p. 236.

    CAS  Google Scholar 

  6. Krokhin, O.V., Smolenkov, A.D., Svintsova, N.V., Obrezkov, O.N., and Shpigun, O.A., J. Chromatogr. A, 1995, vol. 706, nos. 1–2, p. 93.

    Article  CAS  Google Scholar 

  7. Ivanaynen, E.V., Pirogov, A.V., and Shpigun, O.A., Moscow Univ. Chem. Bull., 2009, vol. 64, no. 4, p. 245.

    Article  Google Scholar 

  8. Pirogov, A.V., D’yachkov, I.A., and Shpigun, O.A., Prot. Met. Phys. Chem. Surf., 2011, vol. 47, no. 6, p. 721.

    Article  CAS  Google Scholar 

  9. Domazetis, G., Chromatographia, 1984, vol. 7, p. 383.

    Article  Google Scholar 

  10. Buszewski, B., Jackowska, M., Bocian, S., Kosobuck, P., and Gawdzik, B., Sep. Sci., 2011, vol. 34, p. 601.

    Article  CAS  Google Scholar 

  11. Jackowska, M., Bocian, S., Gawdzik, B., Grochowicz, M., and Buszewski, B., Mater. Chem. Phys., 2011, no. 130, p. 644.

    Google Scholar 

  12. Jackowska, M., Bocian, S., and Buszewski, B., Analyst, 2012, no. 137, p. 4610.

    Google Scholar 

  13. Lin, C., Yang, Y., and Yang, M., J. Chromatogr., 1990, vol. 515, p. 49.

    Article  CAS  Google Scholar 

  14. Rodin, I.A., Smolenkov, A.D., Shpak, A.V., and Shpigun, O.A., Russ. J. Phys. Chem. A, 2007, vol. 81, no. 3, pp. 390–395.

    Article  CAS  Google Scholar 

  15. Chicz, R.M., Shi, Z., and Regier, F.E., J. Chromatogr., 1986, vol. 359, p. 121.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Moscow State University, Moscow, 119991, Russia

    A. A. Loshin, A. V. Zatirakha, A. D. Smolenkov & O. A. Shpigun

Authors
  1. A. A. Loshin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. V. Zatirakha
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. D. Smolenkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. O. A. Shpigun
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. A. Loshin.

Additional information

Original Russian Text © A.A. Loshin, A.V. Zatirakha, A.D. Smolenkov, O.A. Shpigun, 2014, published in Vestnik Moskovskogo Universiteta. Khimiya, 2014, No. 6, pp. 327–336.

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Loshin, A.A., Zatirakha, A.V., Smolenkov, A.D. et al. A novel covalently modified aminated silica-based anion exchanger for ion chromatography. Moscow Univ. Chem. Bull. 69, 245–253 (2014). https://doi.org/10.3103/S0027131414060030

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.3103/S0027131414060030

Keywords

Search

Navigation