Abstract
An automated titration for the Winkler method is presented for measuring primary productivity in the ocean. The system is based on a microcomputer-controlled titration with potentiometric endpoint detection. By the use of 0.005-N sodium thiosulfate as a titrant and a program designed to shorten the time for measuring, the method achieves a precision of 0.04% coefficient of variation with a range of 0.01 to 0.10% for six replicates of samples at oxygen concentration of 70 to 250 μM. It takes about four to five minutes to measure one sample.
Similar content being viewed by others
References
Bradbury, J. H. and A. N. Hambly (1952): An investigation of errors in the amperometric and starch indicator methods for the titration of millinormal solutions of iodine and thiosulfate.Austral. J. Sci. Res., Ser. A,5, 541–554.
Carpenter, J. H. (1965a): The accuracy of the Winkler method for dissolved oxygen analysis.Limnol. Oceanogr.,10, 135–143.
Carpenter, J. H. (1965b): The Chesapeake Bay Institute technique for the Winkler dissolved oxygen method.Limnol. Oceanogr.,10, 141–143.
Culberson, C. H. (1991):Dissolved Oxygen. WHP Operations and Methods, Unpublished manuscript, 15 pp.
Culberson, C. H., and S. Huang (1987): Automated amperometric oxygen titration.Deep-Sea Res.,34, 875–880.
Culberson, C. H., G. Knapp, M. C. Stalcup, R. T. Williams and F. Zemlyak (1991): A comparison of methods for the determination of dissolved oxygen in seawater.WOCE Report 73/91, 77 pp.
Grasshoff, K. (1981): The electrochemical determination of oxygen. p. 329–420. InMarine Electrochemistry, ed. by M. Whitfield and D. Jagner, John Wiley and Sons, New York.
Knowles, G. and G. F. Lowden (1953): Methods for detecting the end-point in the titration of iodine with thiosulfate.Analyst,78, 159–164.
Potter, E. C. (1957): Microdetermination of dissolved oxygen in water. I. Nature of the problem.J. Appl. Chem.,7, 285–297.
Williams, P. J. LeB, and N. W. Jenkinson (1982): A transportable microprocessor-controlled precise Winkler titration suitable for field station and shipboard use.Limnol. Oceanogr.,27, 576–584.
Williams, P. J. LeB., K. R. Heinemann, J. Marra and D. A. Purdie (1983): Comparison of14C and O2 measurements of phytoplankton production in oligotrophic waters.Nature,305, 49–50.
Winkler, L. W. (1888): Die Bestimmung des im Wasser gelösten Sauerstoffen.Ber. Dtsche. Chem. Ges.,21, 2843–2855.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Furuya, K., Harada, K. An automated precise Winkler titration for determining dissolved oxygen on board ship. J Oceanogr 51, 375–383 (1995). https://doi.org/10.1007/BF02285173
Received:
Revised:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02285173