Summary
A previously developed, simple procedure for computer simulation has been applied to non-ideal, linear chromatography. Relations between three different retention measures (the maximum of the peak, the median and the center of gravity) and the skew and the width of the observed elution peak have been suggested from the results of the simulation. These relations are experimentally verified. No one of the retention measures mentioned above is exactly equal to the thermodynamically correct retention volume, but the discrepancy for the median is the smallest.
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Jönsson, J.Å. Non-ideal effects in linear chromatography. Chromatographia 13, 729–733 (1980). https://doi.org/10.1007/BF02265550
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DOI: https://doi.org/10.1007/BF02265550