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Efficiency Maps for Comparing the Properties of Different Chromatographic Systems

  • PHYSICAL CHEMISTRY OF SEPARATION PROCESSES. CHROMATOGRAPHY
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Abstract

Efficiency maps are proposed as plots of the dependence of the peak width at half height Δ1/2 on the function of the sorbate retention factor, obtained from a corrected expression for the efficiency of chromatographic systems for liquid chromatography with the addition of a parameter that takes into account dynamic broadening factors according to the formula \(\Delta _{{1{\text{/}}2}}^{2} = {{a}^{2}} + {{b}^{2}}k(k + 1)\). The efficiency maps can be used to compare various chromatographic systems avoiding the need for an unreasonable choice of random specific conditions of chromatography over the entire range of mobile phase compositions. The efficiency maps are shown to be sensitive to sorbate retention mechanisms.

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REFERENCES

  1. A. J. P. Martin and R. L. M. Synge, Biochem. J. 35, 1358 (1941).

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  2. A. M. Nemirovskii and V. I. Sukhoruchko, Zavod. Lab. 60 (6), 1 (1994).

    CAS  Google Scholar 

  3. V. I. Deineka, Russ. J. Phys. Chem. A 78, 91 (2004).

    Google Scholar 

  4. L. S. Ettre, Pure Appl. Chem. 65, 819 (1993).

    Article  CAS  Google Scholar 

  5. J. J. van Deemter, F. J. Zuiderweg, and A. Klinkenberg, Chem. Eng. Sci. 5, 271 (1958).

    Article  Google Scholar 

  6. V. I. Deineka and A. M. Grigor’ev, Russ. J. Phys. Chem. A 79, 773 (2005).

    CAS  Google Scholar 

  7. E. Katz, K. L. Ogan, and R. P. W. Scott, J. Chromatogr. 270, 51 (1983).

  8. R. P. W. Scott, Liquid Chromatography Column Theory (Wiley, New York, 1992), p. 93.

    Google Scholar 

  9. H. A. Claessens, C. A. M. G. Cramers, and M. A. J. Kuyken, Chromatographia 23, 189 (1987).

    Article  CAS  Google Scholar 

  10. Z. Guo, Z. Sun, N. Zhang, et al., Powder Technol. 354, 842 (2019).

    Article  CAS  Google Scholar 

  11. S. Jung, D. Stoeckel, and U. Tallarek, J. Sep. Sci. 34, 800 (2011).

    Article  CAS  PubMed  Google Scholar 

  12. V. I. Deineka, E. Yu. Oleinits, Ya. Yu. Salasina, I. P. Blinova, and L. A. Deineka, Russ. J. Phys. Chem. A 95, 1729 (2021).

    Article  CAS  Google Scholar 

  13. V. I. Deineka, Anh Van Nguyen, and L. A. Deineka, Russ. J. Phys. Chem. A 93, 2490 (2019).

    CAS  Google Scholar 

  14. V. I. Deineka, L. A. Deineka, I. P. Blinova, et al., Sorbts. Khromatogr. Protsessy 16, 377 (2016).

    CAS  Google Scholar 

  15. A. Vailaya and C. Horváth, J. Chromatogr., A 829, 1 (1998).

  16. W. R. Melander, H.-J. Lin, J. Jacobson, et al., J. Phys. Chem. 88, 4527 (1984).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Belgorod State Research University, 308015, Belgorod, Russia

    V. I. Deineka & I. P. Blinova

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  1. V. I. Deineka
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  2. I. P. Blinova
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Correspondence to V. I. Deineka.

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Deineka, V.I., Blinova, I.P. Efficiency Maps for Comparing the Properties of Different Chromatographic Systems. Russ. J. Phys. Chem. 97, 2577–2581 (2023). https://doi.org/10.1134/S0036024423110067

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  • DOI: https://doi.org/10.1134/S0036024423110067

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