Abstract
Bis(2-silolyl)tetramethyldisiloxane has been obtained by an attempted Wurtz-type coupling of (2-silolyl)dimethylsilyl chloride using sodium metal, and its linear Si−O−Si geometry has been demonstrated by X-ray crystallography.
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References
W. S. Sheldrick, in: The Chemistry of Organic Silicon Compounds, S. Patai and Z. Rappoport (eds.), Wiley, New York (1989), Vol. 1, Chapter 3.
E. Lukevics, O. Pudova, and R. Sturkovich, Molecular Structure of Organosilicon Compounds, Ellis Horwood, Chichester (1989), p. 175.
W. Wojnowski, B. Becker, K. Peters, E. M. Peters, and H. G. Schnering, Z. Anorg. Allg. Chem., 563 (1988).
E. Lukevics, S. Belyakov, L. Ignatovich, and N. Shilina, Bull. Soc. Chim. Fr.,132, 545 (1995).
C. Glidewell and D. C. Liles, Acta Crystallogr.,B34, 124 (1978).
M. G. Voronkov, D. Yu. Nesterov, A. I. Gusev, N. V. Alexeev, and M. B. Lotarev, Dokl. Akad. Nauk SSSR,257, 1377 (1981).
K. Tamao and S. Yamaguchi, Pure Appl. Chem.,68, 139 (1996).
K. Tamao, S. Yamaguchi, and M. Shiro, J. Am. Chem. Soc.,116, 11715 (1994).
Y. Nagai, K. Yamazaki, I. Shiojima, N. Kobori, and M. Hayashi, J. Organomet. Chem.,9, 21 (1967).
W. Ries, T. Albright, J. Silvestre, I. Bernal, W. Malisch, and C. Burschka, Inorg. Chim. Acta,111, 119 (1986).
S. Shambayati, J. F. Blake, S. G. Wierschke, W. L. Jorgensen, and S. L. Schreiber, J. Am. Chem. Soc.,112, 697 (1992), and references cited therein.
S. Yamaguchi and K. Tamao, Bull. Chem. Soc. Jpn.,69, 2327 (1996).
K. Tamao, M. Uchida, T. Izumizawa, K. Furukawa, and S. Yamaguchi, J. Am. Chem. Soc., in press.
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Dedicated to Professor E. Lukevics on the occasion of his 60th birthday.
Institute for Chemical Research, Kyoto University, Uji, Kyoto 611, Japan. Rigaku Corporation, Akishima, Tokyo 196, Japan. Published in Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 180–185, February, 1997.
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Yamaguchi, S., Jin, RZ., Shiro, M. et al. A new example of linear disiloxane: Synthesis and X-ray crystal structure of bis(2-silolyl)tetramethyldisiloxane. Chem Heterocycl Compd 33, 155–160 (1997). https://doi.org/10.1007/BF02256755
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DOI: https://doi.org/10.1007/BF02256755