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New disiloxane based on N-acetylvaline: synthesis and structure

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Abstract

Silylmethylation of N-acetylvaline with the ClCH2SiMe2Cl—(Me3Si)2NH system gave the previously unknown 2-silamorpholin-6-one derivative, whose hydrolysis in aqueous ethanol produced bis-acetylvaline-containing disiloxane. The X-ray diffraction study and quantum chemical calculations demonstrated that both silicon atoms in the final product are four-coordinated.

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Authors and Affiliations

  1. N. I. Pirogov Russian National Research Medical University, 1 ul. Ostrovityanova, 117997, Moscow, Russian Federation

    A. A. Nikolin, A. A. Korlyukov, E. P. Kramarova, D. E. Arkhipov, A. G. Shipov, Yu. I. Baukov & Vad. V. Negrebetsky

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    A. A. Korlyukov & D. E. Arkhipov

Authors
  1. A. A. Nikolin
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  2. A. A. Korlyukov
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  3. E. P. Kramarova
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  4. D. E. Arkhipov
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  5. A. G. Shipov
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  6. Yu. I. Baukov
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  7. Vad. V. Negrebetsky
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Corresponding author

Correspondence to A. A. Nikolin.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1504–1507, August, 2018.

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Nikolin, A.A., Korlyukov, A.A., Kramarova, E.P. et al. New disiloxane based on N-acetylvaline: synthesis and structure. Russ Chem Bull 67, 1504–1507 (2018). https://doi.org/10.1007/s11172-018-2247-8

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  • DOI: https://doi.org/10.1007/s11172-018-2247-8

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