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Mössbauer studies on photoaggregation and photoreduction of tris/β-diketonato/ iron/III/ complexes isolated in low temperature matrices

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Abstract

The state of dispersion and photochemical behaviour of tris/β-diketonato/ iron/III/ complexes isolated in low temperature matrices were characterized by means of57Fe Mössbauer spectroscopy. Tris/acetylacetonato/iron/III/ iron/III/ molecules isolated in a nitrogen matrix were aggregated by photoexcitation. Photoreduction of tris/hexafluoroacetylacetonato/-iron/III/ in solid ethanol was also monitored by the Mössbauer technique.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, The University of Tokyo, Hongo, Tokyo, Japan

    Y. Yamada, Y. Minai, H. Sato & T. Tominaga

Authors
  1. Y. Yamada
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  2. Y. Minai
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  3. H. Sato
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  4. T. Tominaga
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Yamada, Y., Minai, Y., Sato, H. et al. Mössbauer studies on photoaggregation and photoreduction of tris/β-diketonato/ iron/III/ complexes isolated in low temperature matrices. Journal of Radioanalytical and Nuclear Chemistry Letters 87, 359–371 (1984). https://doi.org/10.1007/BF02166794

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  • DOI: https://doi.org/10.1007/BF02166794

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