Abstract
Mössbauer spectroscopy represents a unique method to determine the frequency and the vector of diffusion jumps in solids. The elementary diffusion event can thus be studied in a microscopic way. In order to get maximum information experiments have to be performed on single crystals.
Mössbauer studies of long-range diffusion, on the one hand, have proved the reliability of the method but also demonstrated the considerable technical effort which is necessary. Investigations of localized diffusion (diffusion in a “cage”), on the other hand, have been successful in various fields of physics and biophysics.
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Vogl, G. Diffusion studies. Hyperfine Interact 53, 197–212 (1990). https://doi.org/10.1007/BF02101047
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DOI: https://doi.org/10.1007/BF02101047