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Monolayer vanadia on titania systems from alkoxide precursors. Part II. Activity in primary alcohol oxidation

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Abstract

The activity of V5+ ion monolayers supported on anatase, rutile and anatase-rutile mixed carrier and of bulk V2O5 has been studied in ethanol and n-propanol oxidation. Catalysts exhibited remarkable activity in aldehyde formation. Reaction selectivity was diminished by low temperature combustion.

Abstract

Активность монослоев ионов V5+, нанесенных на анатазу и рутил, а также на смешанные анатазу-рутил, и блочных V2O5 исследовали в окислении зтанола и н-пропанола. Катализаторы проявляют исключительную активность к образованию альдегидов. Селективность реакции понижается за счет низкотемпературного сгорания реактантов.

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References

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Authors and Affiliations

  1. Chemical Faculty, Laboratory of Catalytic Synthesis, Warsaw Technical University (Politechnika), Koszykowa 75, 00-662, Warsaw, Poland

    M. Gliński & J. Kijeński

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  1. M. Gliński
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  2. J. Kijeński
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Gliński, M., Kijeński, J. Monolayer vanadia on titania systems from alkoxide precursors. Part II. Activity in primary alcohol oxidation. React Kinet Catal Lett 46, 387–396 (1992). https://doi.org/10.1007/BF02070962

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  • DOI: https://doi.org/10.1007/BF02070962

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