Abstract
The catalytic activity of vanadium doped TiO2 in the ethylbenzene oxidative dehydrogenation with CO2 was studied experimentally and theoretically. The experimental results showed that the reduction of ethylbenzene conversion and the styrene selectivity was caused by the transition of anatase to rutile phase. Theoretical results showed that the transition of the anatase to rutile phase was mainly caused by vanadium ions and oxygen vacancies.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
M. Sugino, H. Shimada, T. Turuda, H. Miura, N. Ikenaga, and T. Suzuki, Appl. Catal. A 121, 125 (1995).
N. Mimura, I. Takahara, M. Saito, T. Hattori, K. Ohkuma, and M. Ando, Catal. Today 45, 61 (1998).
S. E. Park, J. S. Chang, and J. S. Yoo, in Environmental Challenges and Greenhouse Gas Control for Fossil Fuel Utilization in the 21st Century, Ed. by M. M. Maroto- Valer, Y. Soong, and C. Song (Kluwer Academic, Plenum Press, New York, 2001), pp. 359
F. H. Jones, Surf. Sci. Rep. 42, 75 (2001).
A. Molinari, R. Amadelli, L. Antolini, P. Battioni, and D. Mansuy, J. Mol. Catal. A: Chem. 158, 521 (2000).
M. Pohl, T. Glogowski, S. Kuhn, C. Hessing, and F. Unterumsberger, Mater. Sci. Eng. A 481–482, 123 (2008).
M. Haruta, B. S. Uphade, S. Tsubota, and A. Miyamoto, Res. Chem. Intermed. 24, 329 (1998).
K. Takanabe, K Nagaoka, K. Nariai, and K. I. Aika, J. Catal. 230, 75 (2005).
W. Huang, Z. J. Zuo, P. D. Han, Z. H. Li, and T. D. Zhao, J. Electron. Spectrosc. Relat. Phenom. 173, 88 (2009).
J. S. Chang, S. E. Park, and M. S. Park, Chem. Lett. 26, 1123 (1997).
B. Delley, J. Chem. Phys. 92, 508 (1990).
B. Delley, Phys. Rev. B 66, 155125 (2002).
Y. Wang and D. J. Doren, Solid State Commun. 136, 186 (2005).
R. Janisch and N. A. Spaldin, Phys. Rev. B 73, 035201 (2006).
L. Kavan, M. Grätzel, S. E. Gilbert, C. Klemenz, and H. J. Scheel, J. Am. Chem. Soc. 118, 6716 (1996).
J. P. Perdew and Y. Wang, Phys. Rev. Lett. 66, 508 (1991).
L. E. Depero, J. Solid State Chem. 103, 528 (1993).
L. E. Depero, J. Solid State Chem. 104, 470 (1993).
L. E. Depero, P. Bonzi, M. Musci, and C. Casale, J. Solid State Chem. 111, 247 (1994).
C. H. Douglas and J. M. Merilea, J. Am. Ceram. Soc. 77, 1957 (1994).
Z. J. Zuo, W. Huang, P. D. Han, and Z. H. Li, J. Mol. Struct. 757, 118 (2009).
M. Mazaheri, Z. R. Hesabi, and S. K. Sadrnezhaad, Scripta Mater. 59, 139 (2008).
Z. X. Yang, G. Liu, and R. Q. Wu, Phys. Rev. B 67, 402 (2003).
R. D. Shannon and J. A. Pask, J. Am. Ceram. Soc. 48, 391 (1965).
K. Koshino, N. L. Peterson, and C. L. Wiley, J. Phys. Chem. Solids 46, 1397 (1985).
J. A. Gamboa and D. M. Pasquevich, J. Am. Ceram. Soc. 75, 2934 (1992).
M. J. Readey and D. H. Readey, J. Am. Ceram. Soc. 70, C358 (1987).
R. Asahi, Y. Taga, W. Mannstadt, and A. J. Freeman, Phys. Rev. B 61, 7459 (2000).
M. Lazzeri, A. Vittadini, and A. Selloni, Phys. Rev. B 63, 5409 (2001).
M. Lazzeri, A. Vittadini, and A. Selloni, Phys. Rev. B 65, 9901(E) (2002).
A. Fahmi, C. Minot, B. Silvi, and M. Causa, Phys. Rev. B 47, 11717 (1993).
L. Kavan, M. Grätzel, and J. Rathouský, J. Electrochem. Soc. 143, 394 (1996).
R. W. Godby, M. Schluther, and L. J. Sham, Phys. Rev. B 37, 4170 (1987).
R. D. Shannon, Acta Crystallogr. A 32, 751 (1976).
Author information
Authors and Affiliations
Corresponding author
Additional information
The article is published in the original.
Rights and permissions
About this article
Cite this article
Zhang, H., Bian, H. & Zhang, S. Study on the catalytic activity of vanadium doped TiO2: Anatase-to-rutile phase transition. Russ. J. Phys. Chem. 90, 60–64 (2016). https://doi.org/10.1134/S0036024416010131
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036024416010131