Advertisement

Reaction Kinetics and Catalysis Letters

, Volume 51, Issue 2, pp 459–464 | Cite as

Hydroformylation of olefins catalyzed by rhodium complex anchored on clay matrices

  • S. B. Halligudi
  • K. N. Bhatt
  • K. Venkatasubramanian
Article

Abstract

Investigations on the catalytic activity of a transient Rh(I) triphenylphosphine complex1 anchored on montmorillonite clay have been carried out with respect to hydroformylation of olefins at 70°C and 60 atm of CO+H2 (1:1). The analysis has shown that aldehydes and hydrocarbons of the corresponding olefins result under hydroformylation conditions. In limonene, reaction proceeds with double hydroformylation and hydrogenation to give the respective oxo products. The catalytic activities of1 are compared with Wilkinson's RhI (H) (CO) (PPh3)2 (6) complex in solution under the same hydroformylation conditions.

Keywords

Clay Catalysis Hydrocarbon Aldehyde Catalytic Activity 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    M.C. Baird, J.T. Mague, J.A. Osborn, G. Wilkinson: J. Chem. Soc. (A), 1347 (1967).Google Scholar
  2. 2.
    D. Evans, J.A. Osborn, G. Wilkinson: J. Chem. Soc. (A), 3133 (1968).Google Scholar
  3. 3.
    I. Amer, H. Alper: J. Am. Chem. Soc.,112, 3674 (1990).Google Scholar
  4. 4.
    T. Fuchikami, I. Ojima: J. Am. Chem. Soc.,104, 3527 (1982).Google Scholar
  5. 5.
    A.M. Trzeciak, J.J. Ziólkowski: J. Mol. Catal.,34, 213 (1986).Google Scholar
  6. 6.
    J.A. Osborn, F.H. Jardine, J.F. Young, G. Wilkinson: J. Chem. Soc. (A), 1711 (1966).Google Scholar
  7. 7.
    M.M. Taqui Khan, S.B. Halligudi, K.N. Bhatt, H.C. Bajaj, S.H.R. Abdi: J. Mol. Catal., (1992), in press.Google Scholar
  8. 8.
    S.B. Halligudi, K.N. Bhatt, H.C. Bajaj, M. Krishnaratnam: React. Kinet. Catal. Lett., (1992) in press.Google Scholar
  9. 9.
    M.M. Taqui Khan, S.A. Samad, M.R.H. Siddiqui, H.C. Bajaj, G. Ramachandraiah: Polyhedron, 2729 (1991).Google Scholar

Copyright information

© Akadémiai Kiadó 1993

Authors and Affiliations

  • S. B. Halligudi
    • 1
  • K. N. Bhatt
    • 1
  • K. Venkatasubramanian
    • 1
  1. 1.Catalysis GroupCentral Salt and Marine Chemicals Research InstituteBhavnagarIndia

Personalised recommendations