Abstract
It is found that the lower the Si/Al ratio of ZSM-5 in the catalytic system MgO/ZSM-5, the higher is the activity and selectivity in the reaction of oxidative conversion of methane. The catalytic properties reflect quite closely the basic properties of the samples, studied by means of temperature-programmed desorption of CO2.
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References
P. Levesque, D. Bianchi, R. Le Van Mao and G. Pajonk:Appl. Catal.,57, 31 (1990).
D. Barthomeuf:J. Phys. Chem.,88, 42 (1984).
Y. Amenomiya, V. Birss, M. Goledzinowski, J. Galuszka, A. Sanger:Catal. Rev.-Sci. Engin.,32, 163 (1990).
P. Kovacheva, N. Davidova, A.H. Weiss:Stud. Surf. Sci. Catal.,82, 403 (1994).
P. Kovacheva, N. Davidova, A.H. Weiss:Collect. Czech. Chem. Commun.,57, 2548 (1992).
E. Ruckenstein, A.Z. Khan:J. Catal.,141, 628 (1993).
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Kovacheva, P., Davidova, N. Oxidative conversion of methane over MgO/ZSM-5 catalysts with different Si/Al ratios. React Kinet Catal Lett 59, 41–45 (1996). https://doi.org/10.1007/BF02067990
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DOI: https://doi.org/10.1007/BF02067990