Abstract
Modern methods of nonoxidative methane conversion, as well as catalysts used for this process were considered. The mechanisms of the transformation of the methane molecules on zeolite and metal oxide systems (two-step processes) were discussed. Research results on co-conversion of methane and n-pentane were presented. The influence of the nature of the metal, type of the support, and process conditions on the characteristics of chemisorption and degree of dehydrogenation of methane was demonstrated. The reactivity of the resultant hydrocarbon species in the reaction of formation of aromatic hydrocarbons with n-pentane was studied.
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ACKNOWLEDGMENTS
Physicochemical studies were carried out on the basis of the Omsk Regional Center for Collective Use, Siberian Branch, Russian Academy of Sciences.
Funding
This study was financially supported by the Ministry of Science and Higher Education of the Russian Federation in accordance with the Program of Fundamental Scientific Research of State Academies of Sciences for 2013–2020 in direction V.46, project no. V.46.2.4, Stage 1 (State registration no. in the Unified State Information System of Accounting Civilian Research, Developmental, and Technological Works AAAA-A17-117021450095-1).
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Golinskii, D.V., Vinichenko, N.V., Zatolokina, E.V. et al. Modern Catalysts and Methods of Nonoxidative Methane Conversion. Russ J Gen Chem 90, 1104–1119 (2020). https://doi.org/10.1134/S1070363220060286
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DOI: https://doi.org/10.1134/S1070363220060286