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Study of the steps of acrolein oxidation over a vanadium-molybdenum catalyst

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Abstract

Acrolein is oxidized to acrylic acid over a V−Mo catalyst by lattice oxygen, while the formation of CO2 also involves gas phase oxygen. The steady state of catalyst reduction is about 5% monolayer and is characterized by an oxygen binding energy of 61 kcal/mol.

Abstract

В октслении акролеина в акриловую кислоту на V−Mo-катализаторе участвует решеточный кислород, в образовании CO2 принимает участие также и кислород газовой фазы. Стационарная стелень восстановленности катализатора составляет 5% от монослоя и характеризуется энергией связи кислорода 61 ккал/моль.

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References

  1. E.M. Erenburg, T.V. Andrushkevich, V.N. Bibin: Kinet. Katal.,20, 680 (1979).

    Google Scholar 

  2. G.K. Boreskov: Kinet. Katal.,14, 7 (1973).

    Google Scholar 

  3. Yu.D. Pankratyev, J. Tichy: React. Kinet. Catal. Lett.,2, 319 (1975).

    Google Scholar 

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Popova, G.Y., Andrushkevich, T.V. & Metalkova, G.A. Study of the steps of acrolein oxidation over a vanadium-molybdenum catalyst. React Kinet Catal Lett 12, 469–473 (1979). https://doi.org/10.1007/BF02061756

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  • DOI: https://doi.org/10.1007/BF02061756

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