Abstract
The thermal properties and devitrification behaviour of substituted InF3 glasses were studied by means of differential thermal analysis. A comparison of various simple quantitative methods to assess the level of stability of multicomponent fluoride glass systems was also made. Most of these methods are based on critical temperatures. In this paper, a new parameter,k d(T), is introduced to the stability criteria. The stabilities of several substituted InF3 glasses were evaluated experimentally and correlated with the activation energies of crystallization via this new kinetic criterion and compared with those evaluated by other criteria.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
M. Poulain and J. Lucas, Verres, Refract., 32 (1978) 505.
M. Poulain, M. Chanthanasinh and J. Lucas, Mater. Res. Bull., 12 (1977) 151.
C. T. Moynihan, M. G. Drexhage, B. Bendow, Mater Res. Bull., 16 (1981) 25.
C. M. Baldwin, R. M. Almeida and J. D. Mackenzie, J. Non-Cryst. Solids, 43 (1981) 309.
C. Jacoboni, A. Le Bail and R. De Pape, Glass Technol. 24 (1983) 167.
A. Soufiane and M. Poulain, J. Non-Cryst. Solids, 161 (1993) 206.
C. Charron, G. Fonteneau and J. Lucas, J. Non-Cryst. Solids, 161 (1993) 213.
R. Lebullenger, S. Benjaballah, C. Le Deit and M. Poulain, J. Non-Cryst Solids, 161 (1993) 217.
J. R. Gannon, Proc. SPIE, 266 (1981) 62.
T. Iqbal, M. R. Shahriari and G. H. Sigel Jr, Mater. Sci. Forum, 67&68 (1991) 225.
A. Dietzel, Glasstech. Ber., 22 (1968) 41.
D. R. Uhlmann, J. Non-Cryst. Solids, 7 (1972) 337.
D. R. Uhlmann, J. Non-Cryst. Solids, 25 (1977) 43.
A. Hruby, Czech, J. Phys., B22 (1972) 1187.
M. Saad and M. Poulain, Mater. Sci. Forum 19&20 (1987) 11.
S. Surinach, M. D. Barof, M. T. Clavaguera-Mora and N. Clavaguera, J. Mater. Sci., 19 (1984) 3005.
L. Hu and Z. Jiang, J. Chinese Ceram. Soc., 18 (1990) 315.
A. Marotta, A. Buri and F. Branda, J. Non-Cryst. Solids, 95&96 (1987) 593.
X. Zhao and S. Sakka, J. Non-Cryst. Solids, 95&96 (1987) 487.
F. Branda, A. Marotta and A. Buri, J. Non-Cryst. Solids, 134 (1987) 123.
H. E. Kissinger, Anal. Chem., 29 (1957) 1702.
C. M. Baldwin and J. D. Mackenzie, J. Am. Ceram. Soc., 62 (1979) 537.
M. Poulain, Nature, 293 (1981) 279.
J. F. Cottrant, B. Dubois and J. Portier, Mat. Res. Bull., 20 (1985) 203.
K. Matusita and S. Sakka, J. Non-Cryst. Solids, 38&39 (1980) 741.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Bo, Z., Zhu, J. & Dong, D. Evaluation of the stability of substituted InF3 glasses by differential thermal analysis. Journal of Thermal Analysis 50, 807–814 (1997). https://doi.org/10.1007/BF01979210
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF01979210