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Complexation with diol host compounds. Part 19. Structures and thermal analyses of inclusion compounds oftrans-9,10-dihydroxy-9,10-diphenyl-9,10-dihydroanthracene with dimethylsulphoxide, diethylketone and (±)-2-butanol

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Abstract

The structures of the host compoundtrans-9,10-dihydroxy-9,10-diphenyl-9,10-dihydroanthracene with dimethylsulphoxide (1∶2), diethyl ketone (1∶1) and (±)-2-butanol (1∶1) have been elucidated. Each compound is stabilized by O−H...O hydrogen bonds between host and guest, and the guest molecules are disordered in each structure. The thermal decomposition of the compounds shows them to be relatively unstable.

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Authors and Affiliations

  1. Department of Chemistry, University of Cape Town, 7700, Rondebosch, South Africa

    Leonard J. Barbour, Mino R. Caira & Luigi R. Nassimbeni

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  1. Leonard J. Barbour
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  2. Mino R. Caira
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  3. Luigi R. Nassimbeni
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Barbour, L.J., Caira, M.R. & Nassimbeni, L.R. Complexation with diol host compounds. Part 19. Structures and thermal analyses of inclusion compounds oftrans-9,10-dihydroxy-9,10-diphenyl-9,10-dihydroanthracene with dimethylsulphoxide, diethylketone and (±)-2-butanol. J Chem Crystallogr 24, 539–543 (1994). https://doi.org/10.1007/BF01666734

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  • DOI: https://doi.org/10.1007/BF01666734

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