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Influence of ultrasonic waves on cobaltous hydroxide sol

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Summary

Ultrasonic agency (1 Mc/s 225 watts per sq. cm. output) can be successfully utilised for the preparation of rather a stable colloidal cobaltous hydroxide sol bearing a positive charge. On exposing this sol to ultrasonic waves, it becomes more stable. The specific conductivity and hydrogen ion concentration of the sol continuously increases with the time of exposure to ultrasonic waves. The viscosity of the sol decreases with the time of exposure to ultrasonic waves. The optical density and coagulation values with electrolytes also increase on exposing the sol to ultrasonic waves. The stability of the sol is probably due to the increase in positive charge on the colloidal particles as the hydrogen ion concentration of the sol has increased on exposure. The change in colour is due to transformation of cobaltous to cobaltic hydroxide by ultrasonic waves.

Zusammenfassung

Ultraschallbestrahlung (1 MHz, 225 Watt/cm2) kann erfolgreich zur Präparation stabiler kolloidaler Kobaltohydroxydsole mit positiver Ladung angewandt werden. Bei einer solchen Bestrahlung wird das Sol stabiler. Die spez. Leitfähigkeit und die Wasserstoffionen-Konzentrationen des Sols steigt kontinuierlich mit der Zeit der Ultraschallbestrahlung. Die Viskosität des Sols nimmt entsprechend ab. Die optische Dichte und die Koagulationswerte mit Elektrolyten steigen ebenfalls mit der Bestrahlung.

Die Stabilität des Sols ist wahrscheinlich der Erhöhung der positiven Ladung der Kolloidpartikel zuzuschreiben, da die Wasserstoffionen-Konzentration des Sols mit Bestrahlung steigt. Der Wechsel in der Farbe ist der Umformung von Kobalto- zu Kobaltihydroxyd durch die Ultraschallwellen zuzuschreiben.

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Prakash, S., Pandey, A.D. Influence of ultrasonic waves on cobaltous hydroxide sol. Kolloid-Z.u.Z.Polymere 181, 46–49 (1962). https://doi.org/10.1007/BF01557891

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  • DOI: https://doi.org/10.1007/BF01557891

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