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Characteristics of Nanoparticles in Aqueous Solutions of Acetates and Sulfates of Single and Doubly Charged Cations

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Abstract

This work presents the investigation of ultrasonic speed propagation waves and aqueous solutions densities of acetates and sulfates of single and double- charged cations in a wide range of salt concentration. The variation of the relative adiabatic compressibility of the solution on the salt concentration has two or several straight lines. For each salt at a certain concentration (Cp), the transition from one straight line to another is occurred. Each of these lines corresponds to a certain value of the adiabatic compressibility of water. It is shown that presence of ions decreases the adiabatic compressibility of water. The hydrate numbers and sizes of nanoparticles (hydrated ions) are estimated as a function of the salt concentration. The obtained results show that the number of hydration decreases stepwise with increasing salt concentration, i.e., in certain intervals the salt concentration remains constant. The evaluated hydrate numbers and radii of hydrated ions (nanoparticle sizes) by the acoustic method are in a good agreement with the literature data.

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References

  1. Lee, L.L.: Molecular thermodynamics of electrolyte solutions. World Sci. (2021). https://doi.org/10.1142/6836

    Article  Google Scholar 

  2. Samoilov, O.V.: The structure of aqueous solutions of electrolytes and hydration of ions (translated from Russian). " Izd. Akad. Nauk SSSR, Moscow (1957)

  3. Izutsu, K.: Electrochemistry in nonaqueous solutions translated from Russian, p. 48–92. John Wiley & Sons, US (2009)

    Book  Google Scholar 

  4. Chizhik, V. I. (eds.): NMR-relaxation (translated from Russian), p.154-169. St.-Peterburg (2004)

  5. Smirnov, P.; Trostin, V.: Structural parameters of the nearest environment of ions in aqueous solutions of inorganic electrolytes. JSC Publish. House 67(1), 23–27 (2011). https://doi.org/10.1134/S1070363213010039

    Article  Google Scholar 

  6. Afanasyev, V.N.; Ustinov, N.: Verification of electrolyte solvation from diluted to concentrated in aqueous solutions (translated from Russian). Bull. Moscow State Univ. 52, 323–340 (2021)

    Google Scholar 

  7. Nizomov, Z.A.; Badalov, A.; Mirzoeva, Sh.: Estimation of the hydration numbers of doubly charged cations in aqueous solutions of nitrate salts from ultrasonic data (translated from Russian). Rep. Acad. Sci. Republic of Tajikistan 46, 76–78 (2013)

    Google Scholar 

  8. Burakowski, A.; Gliński, J.: Hydration of urea and its derivatives from acoustic and volumetric methods. Chem. Phys. Lett. 641, 40–43 (2015). https://doi.org/10.1016/j.cplett.2015.10.052

    Article  Google Scholar 

  9. Dilip, H.; Barge, S.: Hydrogen bonding in liquid water and in the hydration shell of salts. ChemPhysChem 17, 902–912 (2016). https://doi.org/10.1002/cphc.201500921

    Article  Google Scholar 

  10. Huang, X.; Cao, Z.; Wang, Q.: The universal characteristic water content of aqueous solutions. Chinese Phys. B 28, 065101 (2019). https://doi.org/10.1088/1674-1056/28/6/065101

    Article  Google Scholar 

  11. Vo, Q.; Bay, M.; Nam, P.; Quang, D.; Flavel, M.; Hoa, N.; Mechler, A.: Theoretical and experimental studies of the antioxidant and antinitrosant activity of syringic acid. J. Org. Chem. 85, 15514–15520 (2020). https://doi.org/10.1021/acs.joc.0c02258

    Article  Google Scholar 

  12. Traustason, H.: Prediction of solution behavior via calorimetric measurements allows for detailed elucidation of polyoxometalate transformation. Inorg. Chem. 60, 6753–6763 (2021). https://doi.org/10.1021/acs.inorgchem.1c00587

    Article  Google Scholar 

  13. Kaatze, U.: Aspects of Ion hydration. adiabatic compressibility compared to the dielectric properties of aqueous electrolyte solutions. J. Phys. Chem. B 117, 12252–12260 (2013). https://doi.org/10.1021/jp407633c

    Article  Google Scholar 

  14. Krakowiak, J.; Wawer, J.; Panuszko, A.: Densimetric and ultrasonic characterization of urea and its derivatives in water. J. Chem. Thermodynam. 58, 211–220 (2013)

    Article  Google Scholar 

  15. Afanasiev, V.N.; Ustinov, A.N.: Solvation of the electrolytic component of Seawater. J. Solution Chem. 36, 853–868 (2007). https://doi.org/10.1007/s10953-007-9152-3

    Article  Google Scholar 

  16. Mikhailov, I.; Soloviev, V.; Syrnikov, Yu.: Fundamentals of Molecular Acoustics. Nauka, Moscow (1964)

    Google Scholar 

  17. Nizomov, Z.; Salnikova, A.: Interparticle interactions in aqueous solutions of sulfates according to IR – spectroscopy (translated from Russian). Rep. Acad. Sci. Republic of Tajikistan 44, 74–78 (2021)

    Google Scholar 

  18. Sarkisov, G.N.: Structural models of water (translated from Russian). Uspekhi fizicheskikh nauk 176, 833–845 (2016)

    Article  Google Scholar 

  19. Antonchenko, V.; Davydov, A.; Ilyin, V. (eds.). Fundamentals of Water Physics (translated from Russian), p.600-667. Kiev: Nauk. Dumka (1991)

  20. Henke, D.E.: A history of ordinary and extraordinary means. Natl Catholic Bioethics Q 5(3), 555–575 (2005). https://doi.org/10.5840/ncbq20055333

    Article  Google Scholar 

  21. Malenkov, G.G.: Structure and dynamics of liquid water. J. Struct. Chem. 47, 5–35 (2006). https://doi.org/10.1007/s10947-006-0375-8

    Article  Google Scholar 

  22. Lyashchenko, A.K.; Dunyashev, L.V.; Dunyashev, V.S.: Spatial structure of water in the entire area of the close order. J. Struct. Chem. 47, 36–53 (2006)

    Google Scholar 

  23. Wiggins, P.M.: Role of water in some biological processes. Microbiol. Rev. 54(4), 432–449 (1990). https://doi.org/10.1128/mr.54.4.432-449.1990

    Article  Google Scholar 

  24. Samoilov, OYa.: To the fundamentals of the kinetic theory of hydrophobic hydration in dilute aqueous solutions (translated from Russian). J. Phys. Chem. 52, 1857–1862 (1978)

    Google Scholar 

  25. Marcus, Y.: Effect of ions on the structure of water: structure making and breaking. Chem. Rev. 109(3), 1346–1370 (2019). https://doi.org/10.1021/cr8003828

    Article  Google Scholar 

  26. Grechishkina, AYu.; Kazimirov, V.P.; Goncharuk, V.V.: Influence of the nature and geometry of ions on the structure of the solvent in aqueous solutions of electrolytes (translated from Russian). J. Chem. Technol. Water 29, 413–421 (2007)

    Article  Google Scholar 

  27. Grossfield, A.: Dependence of ion hydration on the sign of the ions charge. J. Chem. Phys. 122(2), 024506 (2005). https://doi.org/10.1063/1.1829036

    Article  Google Scholar 

  28. Ollis, D.F.: Kinetics of liquid phase photocatalyzed reactions: an illuminating approach. J. Phys. Chem. B 109(6), 2439–2444 (2005). https://doi.org/10.1021/jp040236f

    Article  Google Scholar 

  29. Feliu, S.: Electrochemical impedance spectroscopy for the measurement of the corrosion rate of magnesium alloys: brief review and challenges. Metals 10(6), 775 (2020). https://doi.org/10.3390/met10060775

    Article  Google Scholar 

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Acknowledgements

The authors express their gratitude to the leadership of the Research Institute of the Tajik National University for the opportunity to conduct this study in the laboratory of condensed matter physics and molecular spectroscopy.

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No funding to declare. This research received no specific grant from any funding agency in the public, commercial, or not-for-profit sectors.

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Authors and Affiliations

  1. Tajik national University, 734025, Dushanbe, Tajikistan

    Ziyovuddin Nizomov & Muhammadumar Asozoda

  2. S.U.Umarov Physical-Technical Institute of NAST, 734025, Dushanbe, Tajikistan

    Ziyovuddin Nizomov & Dilshod Nematov

  3. M.S.Osimi Tajik Technical University, 734025, Dushanbe, Tajikistan

    Dilshod Nematov

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  1. Ziyovuddin Nizomov
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  2. Muhammadumar Asozoda
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  3. Dilshod Nematov
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Correspondence to Dilshod Nematov.

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Nizomov, Z., Asozoda, M. & Nematov, D. Characteristics of Nanoparticles in Aqueous Solutions of Acetates and Sulfates of Single and Doubly Charged Cations. Arab J Sci Eng 48, 867–873 (2023). https://doi.org/10.1007/s13369-022-07128-2

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