Summary
A comparison is presented between the qualitative predictions of the various theories of steric stabilization with the results of experiments. It is shown that with the notable exception ofFischer's solvency theory, all of the theories advanced to-date are at odds with results of experiments.
Possible reasons for these discrepancies are discussed.
Similar content being viewed by others
References
Heller, W. andT. L. Pugh, J. Chem. Phys.22, 1778 (1954).
Heller, W., Pure Appl. Chem.12, 249 (1966).
Zsigmondy, R., Z. anal. Chem.40, 697 (1901).
Napper, D. H., Trans. Faraday Soc.64, 1701 (1968).
Napper, D. H., J. Colloid Interface Sci.32, 106 (1970).
Napper, D. H., J. Colloid Interface Sci.33, 384 (1970).
Napper, D. H. andA. Netschey, J. Colloid Interface Sci.37, 528 (1971).
Evans, R., J. B. Davison, andD. H. Napper, J. Polymer Sci. B10, 449 (1972).
Fischer, E. W., Kolloid-Z.160, 120 (1958).
Mackor, E. L., J. Colloid Sci.6, 492 (1951).
Mackor, E. L. andJ. H. van der Waals, J. Colloid Sci.7, 535 (1952).
Clayfield, E. J. andE. C. Lumb, Disc. Faraday Soc.42, 314 (1966).
Clayfield, E. J. andE. C. Lumb, J. Colloid Sci.22, 269 (1966).
Clayfield, E. J. andE. C. Lumb, J. Colloid Sci.22, 285 (1966).
Clayfield, E. J. andE. C. Lumb, Macromolecules1, 133 (1968).
Elworthy, P. H., A. T. Florence, andJ. A. Rogers, J. Colloid Interface Sci.35, 23 (1971).
Elworthy, P. H., A. T. Florence, andJ. A. Rogers, J. Colloid Interface Sci.35, 34 (1971).
Shaw, D. J., Introduction to Colloid and Surface Chemistry, p. 185 (1970).
Napper, D. H., Kolloid-Z. u. Z. Polymere234, 1149 (1969).
Meier, D. J., J. Phys. Chem.71, 1861 (1967).
Hesselink, F. Th., J. Phys. Chem.73, 3488 (1969).
Hesselink, F. Th., J. Phys. Chem.75, 65 (1971).
Hesselink, F. Th., A. Vrij, andJ. Th. G. Overbeek, J. Phys. Chem.75, 2094 (1971).
Deryagin, B. V., Kolloid-Z.69, 155 (1934).
Flory, P. J., Principles of Polymer Chemistry, Chap. 14 (New York 1953).
Molau, G. E., Kolloid-Z. u. Z. Polymere238, 493 (1970).
Molau, G. E., J. Polymer Sci. A3, 1267 (1965).
Molau, G. E., J. Polymer Sci. A3, 4235 (1965).
Dobbie, J. W. andD. H. Napper, unpublished observations (1972).
Smitham, J. B., B. Sc. Honours Thesis, University of Sydney (1972).
Ottewill, R. H. andT. W. Walker, Kolloid-Z. u. Z. Polymere227, 108 (1968).
Gibson, D. V., B. Sc. Honours Thesis, University of Sydney (1971).
Flory, P. J. andW. R. Krigbaum, J. Chem. Phys.18, 1086 (1950).
Flory, P. J., Principles of Polymer Chemistry, p. 525 (New York 1953).
Doroszkowski, A. andR. Lambourne, J. Polymer Sci. C34, 253 (1971).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Evans, R., Napper, D.H. Steric stabilization I. Kolloid-Z.u.Z.Polymere 251, 409–414 (1973). https://doi.org/10.1007/BF01498687
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01498687