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Steric stabilization I

Comparison of theories with experiment

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Summary

A comparison is presented between the qualitative predictions of the various theories of steric stabilization with the results of experiments. It is shown that with the notable exception ofFischer's solvency theory, all of the theories advanced to-date are at odds with results of experiments.

Possible reasons for these discrepancies are discussed.

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References

  1. Heller, W. andT. L. Pugh, J. Chem. Phys.22, 1778 (1954).

    Google Scholar 

  2. Heller, W., Pure Appl. Chem.12, 249 (1966).

    Google Scholar 

  3. Zsigmondy, R., Z. anal. Chem.40, 697 (1901).

    Google Scholar 

  4. Napper, D. H., Trans. Faraday Soc.64, 1701 (1968).

    Google Scholar 

  5. Napper, D. H., J. Colloid Interface Sci.32, 106 (1970).

    Google Scholar 

  6. Napper, D. H., J. Colloid Interface Sci.33, 384 (1970).

    Google Scholar 

  7. Napper, D. H. andA. Netschey, J. Colloid Interface Sci.37, 528 (1971).

    Google Scholar 

  8. Evans, R., J. B. Davison, andD. H. Napper, J. Polymer Sci. B10, 449 (1972).

    Google Scholar 

  9. Fischer, E. W., Kolloid-Z.160, 120 (1958).

    Google Scholar 

  10. Mackor, E. L., J. Colloid Sci.6, 492 (1951).

    Google Scholar 

  11. Mackor, E. L. andJ. H. van der Waals, J. Colloid Sci.7, 535 (1952).

    Google Scholar 

  12. Clayfield, E. J. andE. C. Lumb, Disc. Faraday Soc.42, 314 (1966).

    Google Scholar 

  13. Clayfield, E. J. andE. C. Lumb, J. Colloid Sci.22, 269 (1966).

    Google Scholar 

  14. Clayfield, E. J. andE. C. Lumb, J. Colloid Sci.22, 285 (1966).

    Google Scholar 

  15. Clayfield, E. J. andE. C. Lumb, Macromolecules1, 133 (1968).

    Google Scholar 

  16. Elworthy, P. H., A. T. Florence, andJ. A. Rogers, J. Colloid Interface Sci.35, 23 (1971).

    Google Scholar 

  17. Elworthy, P. H., A. T. Florence, andJ. A. Rogers, J. Colloid Interface Sci.35, 34 (1971).

    Google Scholar 

  18. Shaw, D. J., Introduction to Colloid and Surface Chemistry, p. 185 (1970).

  19. Napper, D. H., Kolloid-Z. u. Z. Polymere234, 1149 (1969).

    Google Scholar 

  20. Meier, D. J., J. Phys. Chem.71, 1861 (1967).

    Google Scholar 

  21. Hesselink, F. Th., J. Phys. Chem.73, 3488 (1969).

    Google Scholar 

  22. Hesselink, F. Th., J. Phys. Chem.75, 65 (1971).

    Google Scholar 

  23. Hesselink, F. Th., A. Vrij, andJ. Th. G. Overbeek, J. Phys. Chem.75, 2094 (1971).

    Google Scholar 

  24. Deryagin, B. V., Kolloid-Z.69, 155 (1934).

    Google Scholar 

  25. Flory, P. J., Principles of Polymer Chemistry, Chap. 14 (New York 1953).

  26. Molau, G. E., Kolloid-Z. u. Z. Polymere238, 493 (1970).

    Google Scholar 

  27. Molau, G. E., J. Polymer Sci. A3, 1267 (1965).

    Google Scholar 

  28. Molau, G. E., J. Polymer Sci. A3, 4235 (1965).

    Google Scholar 

  29. Dobbie, J. W. andD. H. Napper, unpublished observations (1972).

  30. Smitham, J. B., B. Sc. Honours Thesis, University of Sydney (1972).

  31. Ottewill, R. H. andT. W. Walker, Kolloid-Z. u. Z. Polymere227, 108 (1968).

    Google Scholar 

  32. Gibson, D. V., B. Sc. Honours Thesis, University of Sydney (1971).

  33. Flory, P. J. andW. R. Krigbaum, J. Chem. Phys.18, 1086 (1950).

    Google Scholar 

  34. Flory, P. J., Principles of Polymer Chemistry, p. 525 (New York 1953).

  35. Doroszkowski, A. andR. Lambourne, J. Polymer Sci. C34, 253 (1971).

    Google Scholar 

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Evans, R., Napper, D.H. Steric stabilization I. Kolloid-Z.u.Z.Polymere 251, 409–414 (1973). https://doi.org/10.1007/BF01498687

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  • DOI: https://doi.org/10.1007/BF01498687

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