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Spectral effects of intramolecular interaction in the chloranhydrides of unsaturated phosphorus acids

1. Raman-spectrum characteristics of unsaturated groups

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Abstract

Measurements have been made of the integral Raman line strength of unsaturated phosphorus acids; it is concluded that the phosphorus-bearing group interacts with theπ-electron system of the aromatic radical in the excited state. It is found that the -PCl2, -P(O)Cl2 and -P(S) · Cl2 will show acceptor behavior in the conjugated system when interacting with donor substituents. The role of the vacant orbitals of the chlorine attached to the phosphorus is discussed.

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Authors and Affiliations

  1. A. A. Zhdanov Irkutsk University, USSR

    V. V. Dorokhova, G. V. Patovskii, B. V. Tomikhin, E. F. Grechkin & A. V. Kalabina

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  1. V. V. Dorokhova
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  2. G. V. Patovskii
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  3. B. V. Tomikhin
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  4. E. F. Grechkin
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  5. A. V. Kalabina
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Translated from Izvestiya Vysshikh Uchebnykh Zavedenii Fizika, No. 11, pp. 25–28, November, 1972.

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Dorokhova, V.V., Patovskii, G.V., Tomikhin, B.V. et al. Spectral effects of intramolecular interaction in the chloranhydrides of unsaturated phosphorus acids. Soviet Physics Journal 15, 1553–1556 (1972). https://doi.org/10.1007/BF01231222

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  • DOI: https://doi.org/10.1007/BF01231222

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