Skip to main content
SpringerLink
Log in

Hysteresis of Corrole Fluorescence in Acid–Base Equilibria

  • Published:
Journal of Applied Spectroscopy Aims and scope

The effect of sequential formation of protonated and deprotonated forms of 2,3,7,13,17,18-hexamethyl-8,12-di-n-butylcorrole in solution on their photophysical characteristics and spectral-luminescent properties was studied. The spectral characteristics of each of the two forms in the ground electronic state were found to be the same when they formed from the free base and from the antipodal form, while the fluorescence spectra of the two forms differed depending on the method of formation. Based on an analysis of spectral shifts in fluorescence spectra and fluorescence quantum yields, it was concluded that the protonated and deprotonated forms of corroles underwent specific interactions in the lower excited singlet S1 state due to the formation of a complex solvation shell. These specific interactions were shown to lead to hysteresis of the fluorescence characteristics of the protonated and deprotonated forms of corroles with their mutual transitions caused by (cyclic) changes in the acid–base equilibrium.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Yu. B. Ivanova, V. A. Savva, N. Zh. Mamardashvili, A. S. Starukhin, T. H. Ngo, W. Dehaen, W. Maes, and M. M. Kruk, J. Phys. Chem. A, 116, 10683–10694 (2012).

    Article  Google Scholar 

  2. M. M. Kruk, T. H. Ngo, P. Verstappen, A. S. Starukhin, J. Hofkens, W. Dehaen, and W. Maes, J. Phys. Chem. A, 116, 10695–10703 (2012).

    Article  Google Scholar 

  3. W. J. D. Beenken, M. Presselt, T. H. Ngo, W. Dehaen, W. Maes, and M. M. Kruk, J. Phys. Chem. A, 118, 862–871 (2014).

    Article  Google Scholar 

  4. M. Roucan, M. Keilmann, S. J. Connon, S. S. R. Bernhard, and M. O. Senge, Chem. Commun., 54, 26–29 (2018).

    Article  Google Scholar 

  5. M. Keilmann and M. O. Senge, Angew. Chem., Int. Ed., 58, 418–441 (2019).

  6. K. Norvaisa, K. J. Flanagan, D. Gibbons, and M. O. Senge, Angew. Chem., Int. Ed., 58, 16553–16557 (2019).

  7. K. Norvaisa and M. O. Senge, Chem. Proc., 5, 32–39 (2021)

    Google Scholar 

  8. J. Takeda and M. Sato, Chem. Lett., 11, 971–972 (1995).

    Article  Google Scholar 

  9. M. M. Kruk, J. Appl. Spectrosc., 89, 624–630 (2022).

    Article  ADS  Google Scholar 

  10. A. E. Likhonina, M. B. Berezin, M. A. Krest′yaninov, and D. B. Berezin, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 64, 29–39 (2021).

  11. Yu. B. Ivanova, S. G. Pukhovskaya, N. Zh. Mamardashvili, O. I. Koifman, and M. M. Kruk, J. Mol. Liq., 275, 491–498 (2019).

    Article  Google Scholar 

  12. M. M. Kruk, S. G. Pukhovskaya, Yu. B. Ivanova, and O. I. Koifman, Russ. Chem. Bull., Int. Ed., 69, 1072–1075 (2020).

  13. N. N. Kruk, Tr. BGTU, Ser. 3: Fiz.-Mat. Nauki Inf., 272, 1–6 (2023).

  14. G. I. Vargas-Zuniga and J. L. Sessler, Coord. Chem. Rev., 345, 281–286 (2017).

    Article  Google Scholar 

  15. M. M. Kruk, A. S. Starukhin, N. Zh. Mamardashvili, V. B. Sheinin, and Yu. B. Ivanova, J. Appl. Spectrosc., 74, 831–837 (2007).

    Article  ADS  Google Scholar 

  16. M. M. Kruk, Yu. B. Ivanova, V. B. Sheinin, A. S. Starukhin, N. Zh. Mamardashvili, and O. I. Koifman, Macroheterocycles, 1, 50–58 (2008).

    Article  Google Scholar 

  17. M. M. Kruk, A. S. Starukhin, N. Zh. Mamardashvili, G. M. Mamardashvili, Y. B. Ivanova, and O. V. Maltseva, J. Porphyrins Phthalocyanines, 13, 1148–1158 (2009).

    Article  Google Scholar 

  18. Yu. B. Ivanova, N. N. Kruk, A. S. Starukhin, and N. Zh. Mamardashvili, Ross. Khim. Zh., Zh. Ross. Khim. O'va im. D. I. Mendeleeva, LIII, 47–55 (2009).

  19. D. V. Petrova, A. S. Semeikin, N. M. Berezina, M. B. Berezin, and M. I. Bazanov, Macroheterocycles, 12, 119–128 (2019).

    Article  Google Scholar 

  20. Y. H. Ajeeb, D. V. Klenitsky, I. V. Vershilovskaya, D. V. Petrova, A. S. Semeikin, W. Maes, L. L. Gladkov, and M. M. Kruk, J. Appl. Spectrosc., 87, 421–427 (2020).

    Article  ADS  Google Scholar 

  21. L. L. Gladkov, D. V. Klenitsky, and M. M. Kruk, Organics, 4, 490–502 (2023).

    Article  Google Scholar 

  22. A. Yu. Shakel′, A. M. Sokhibova, D. V. Petrova, A. S. Semeikin, and N. N. Kruk, Tr. BGTU, Ser. 3: Fiz.-Mat. Nauki Inf., 260, 36–42 (2022).

  23. D. B. Berezin, D. R. Karimov, and A. V. Kustov, Corroles and Their Derivatives: Synthesis, Properties, Potential for Practical Use [in Russian], LENAND, Moscow (2018).

    Google Scholar 

  24. M. M. Kruk, D. V. Klenitsky, and W. Maes, Macroheterocycles, 12, 58–67 (2019).

    Article  Google Scholar 

  25. M. M. Kruk, A. S. Starukhin, and W. Maes, Macroheterocycles, 4, 69–79 (2011).

    Article  Google Scholar 

  26. V. N. Knyukshto, L. L. Gladkov, W. Maes, and M. M. Kruk, J. Appl. Spectrosc., 90, 507–514 (2023).

    Article  ADS  Google Scholar 

  27. A. P. Losev, E. I. Sagun, and I. N. Nichiporovich, Khim. Fiz., 6, 907–914 (1987).

    Google Scholar 

  28. E. I. Sagun, Khim. Fiz., 9, 764–777 (1990).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Belarusian State Technological University, Minsk, Belarus

    A. Yu. Shakel, A. M. Sokhibova & M. M. Kruk

  2. Institute for Physics of Microstructures, Russian Academy of Sciences, Nizhny Novgorod, Russia

    D. V. Petrova

  3. Ivanovo State University of Chemistry and Technology, Ivanovo, Russia

    D. V. Petrova

Authors
  1. A. Yu. Shakel
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. M. Sokhibova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. D. V. Petrova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. M. Kruk
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to M. M. Kruk.

Additional information

Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 91, No. 2, pp. 177– 183, March–April, 2024.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Shakel, A.Y., Sokhibova, A.M., Petrova, D.V. et al. Hysteresis of Corrole Fluorescence in Acid–Base Equilibria. J Appl Spectrosc 91, 261–266 (2024). https://doi.org/10.1007/s10812-024-01715-x

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10812-024-01715-x

Keywords

Search

Navigation