Summary
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1.
In a calorimeter with constant heat exchange we have measured isotherms and differential heats of adsorption of acetone, diethyl ether and acetic acid on a graphitized thermal black. At the start the isotherms are concave and the differential heats when plotted versus the amount adsorbed pass through a maximum.
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2.
The mutual interaction between these adsorbates in an adsorbed layer increases in the sequence from diethyl ether to acetone and acetic acid: this interaction originates from dispersional and electrostatic forces and in the case of acetic acid also from hydrogen bonds leading to the formation of dimers on the surface.
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3.
The theoretically calculated energies of the adsorption forces are in agreement with the heats of adsorption and give the right sequence for the various adsorbates.
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Literature cited
A. V. Kizelev, Zh. fiz. khimii 35. 233 (1961).
Handbook of Chemistry, Vol. I (Moscow-Leningrad, Goskhimizdat, 1951) p. 858.
E. W. Johnson and L. K. Nash, J. Amer. Chem, Soc.72, 547 (1950).
W. O. Miligan and H. B. Whitehurst, J. Phys. Chem.56, 1073 (1952).
A. V. Kiselev and V. L. Lygin. Kolloidn. zh.23, 157 (1961).
O. M. Dzhigit, A. V. Kiselev, and G. G. Muttik, Kolloidn. zh.23, 553 (1961).
N. N. Avgul'. G. L Berezin, A. V. Kiselev, and I. A. Lygina, Izv. AN SSSR, Otd. khim. n, 205(1961). N. N. Avgul', A. V. Kiselev, and I. A. Lygina, Izv. AN SSSR, Otd. khim. n. 1404(1961).
N. N. Avgul', A. V. Kiselev, and I. A. Lygina, Kolloidn. zh.23, 369 (1961).
A. A. Isirikyan and A. V. Kiselev, Kolloidn. zh.23, 281 (1961).
A. V. Kiselev and E. V. Khrapova, Kolloidn. zh.23, 163 (1961).
N. N. Avgul', A. V. Kiselev. and L. A. Lygina, Kolloidn. zh.23, 513 (1961).
N. N. Avgul', G. L. Berezin, A. V. Kiselev, L. A. Lygina. and G. G. Muttlk, Zh. fiz. khimii31, 1111 (1957).
S. Brunauer, P. H. Emmett. and E. Teller, J. Amer. Chem. Soc.60, 309 (1938).
N. N. Avgul', A. V. Kiselev, and I. A. Lygina. Izd, AN SSSR, Otd. khim. n. 1395(1961).
Landolt-Börnstein, Tabellen. 6 Aufl., I. Bd. 4, Teil,1951, s. 531–533.
A. V. Kiselev, Kolloidn. zh.20, 338 (1958); A. V. Kiselev, N. V. Kovaleva, V. A. Sinitsyn, and E. V. Khrapova, Kolloidn. zh.20, 444 (1958); A. V. Kiselev and D. P. Poshkus, Izv. AN SSSR. Otd. khim. n. 520(1958).
T. Hill, L Chem. Phys,14, 441 (1946).
A. V. Kiselev and A. A. Isirikyan. J. Phys. Chem.65, 601 (1961).
A. V. Kiselev and D. P. Poshkus. Dokl. AN SSSR.132, 876 (1960);139, 1145 (1961).
N. N. Avgul', G. I. Berezin, A. V. Kiselev, and I. A. Lygina, Izv. AN SSSR, Otd. khim. n. 1021(1957).
N. N. Avgul', A. A. Isirikyan, A. V. Kiselev, I. A. Lygina, and D. P. Poshkus, Izv. AN SSSR, Otd. khim. n. 1314(1957); 1196(1959).
G. C. Pimentai and A. L. McCellan, The Hydrogen Bond, San Francisco and London, 1960.
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Avgul', N.N., Klselev, A.V. & Lygina, I.A. Adsorption and heat of adsorption of diethyl ether. acetone and acetic acid vapors on graphitized carbon black. Russ Chem Bull 10, 1977–1984 (1961). https://doi.org/10.1007/BF01182938
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DOI: https://doi.org/10.1007/BF01182938