Summary
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1.
The heats of combustion of tetramethyl- and tetraethyltin were determined and their heats of formation from their elements and the Sn-C bond energy were calculated. The heats of formation found introduced greater regularity in the homologous series than the results of previous investigators.
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2.
It was shown that the calorimetric procedure used is suitable for the determination of heats of combustion of organometallic compounds with a sufficiently high degree of accuracy. However, an individual approach is necessary to the combustion procedure to be applied in the case of every compound investigated, and it is therefore necessary to carry out numerous preliminary experiments.
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3.
The Raman spectrum of tetraethyltin was determined for the first time.
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Balandin, A.A., Klabunovskii, E.I., Kozina, M.P. et al. Thermochemical determination of bond energies Communication 1. Sn-C bond energies in tetrametayl- and tetraethyltin. Russ Chem Bull 7, 10–15 (1958). https://doi.org/10.1007/BF01170854
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DOI: https://doi.org/10.1007/BF01170854