Summary
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1.
The alkali -stabilities of glasses of the type (87 -−x)%SiO2, −x%RO, 13%Na2O (R is Be, Mg, Ca, Sr, Ba, Zn, Cd, or Pb), binary sodium silicate glasses containing 13–33 moles %Na2O, and titanium-containing flint glasses were determined by measuring the thickness of the dissolved layer interferometrically.
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2.
It was shown that, with the exception of beryllium oxide, all oxides introduced into the binary glass in place of silica lower the alkali-stability of the glass. At first (up to 22 % RO), the lowering is only slight and the glasses differ little in alkali-stability. When the amount of silica replaced by metal oxide is higher than this, there is a considerable fall in stability; this fall is the greater, the greater the ionic radius of the metal introduced (ionic-radius rule).
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3.
For sodium oxide contents of up to 20 moles percent, binary sodium silicate glasses are fairly stable. Titanium affects stability to alkali in the same way as lead.
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Molchanov, V.S., Prikhid'ko, N.E. Corrosion of silicate glasses by alkaline solutions Communication 2. Relation between the stability of glasses to alkali and their compositions. Russ Chem Bull 7, 1–4 (1958). https://doi.org/10.1007/BF01170852
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DOI: https://doi.org/10.1007/BF01170852