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Synthesis of adamantyl-substituted pyrazolines

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Chemistry of Heterocyclic Compounds Aims and scope

Summary

The reaction of a series of N-R-N-RI-1(β-aminopropionyl)adamantanes with pheny1hydrazine formed 3(adamantyl-I)-1 phenylpyrazoline, the structure of which was confirmed by reverse synthesis from adamantyl-1 vinyl ketone. It is shown that the nitroso derivative of the secondary 0-amino ketone is also cyclized into 3(adamantyl-1)-1-phenylpyrazoline.

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Authors and Affiliations

  1. Samara State Technical University, 443010, Samara

    N. V. Makarova, N. N. Zemtsova & I. K. Moiseev

Authors
  1. N. V. Makarova
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  2. N. N. Zemtsova
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  3. I. K. Moiseev
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1038-1040, August, 1994.

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Makarova, N.V., Zemtsova, N.N. & Moiseev, I.K. Synthesis of adamantyl-substituted pyrazolines. Chem Heterocycl Compd 30, 892–894 (1994). https://doi.org/10.1007/BF01165025

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  • DOI: https://doi.org/10.1007/BF01165025

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