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Polyfuryl(aryl)alkanes and their derivatives. 13. Molecular structure of bis(5-methyl-2-furyl)(4-methoxyphenyl)methane and tris(5-methyl-2furyl)methane

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Abstract

4-Methoxyphenylbis(5-methyl-2-furyl)methane (I) and tris(5-methyl-2-furyl)methane (II) were investigated by x-ray crystallographic analysis. It was established that the molecules of (I) have a propeller conformation with Cs symmetry, and the furan rings are turned with the oxygen atoms towards the methine hydrogen atom. The molecule of (II) has a different conformation with C2v symmetry; one of the furan rings and the methine C-H bond lie ideally in one plane, and the other two furan rings are arranged symmetrically with the oxygen atoms in relation to this bond and incline toward eclipsing of the exocyclic C-C bond.

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References

  1. A. V. Butin, T. A. Stroganova, and V. G. Kul'nevich, Khim. Geterotsikl. Soedin., No. 2, 175 (1996).

  2. M. I. Aroney, R. J. W. Le Fevre, G. L. D. Ritchie, and A. N. Singh, J. Chem. Soc., No. 11, 5810 (1965).

  3. V. V. Korshak, Yu. V. Kolodyazhnyi, V. A. Vasnev, S. V. Vinogradov, N. N. Tsapkova, M. M. Danashvili, S. B. Bulgarevich, and A. P. Sadimenko, Dokl. Akad. Nauk SSSR,253, No. 5, 1140 (1980).

    Google Scholar 

  4. J. D. Andose, and K. J. Mislow, J. Am. Chem. Soc.,96, No. 7, 2168 (1974).

    Google Scholar 

  5. P. C. Riche and B. C. Pascard, Acta Cryst.,30, No. 7, 1874 (1974).

    Google Scholar 

  6. D. Ya. Movshovich, N. A. Ivanova, S. B. Bulgarevich, A. V. Butin, and V. G. Kul'nevich, Zh. Obshch. Khim.,61, No. 10, 2349 (1991).

    Google Scholar 

  7. A. Bondi, J. Phys. Chem.,70, No. 9, 3006 (1966).

    Google Scholar 

  8. É. Ya. Lukevits (ed.), Advances in Furan Chemistry [in Russian], Zinatne, Riga (1978).

    Google Scholar 

  9. K. Eriks and L. L. Kon, Petrol. Res. Fund. Rep., No. 8, 5 (1963).

  10. A. V. Butin, V. G. Kul'nevich, V. T. Abaev, N. G. Mikhailyuchenko, A. V. Shpakov, O. Yu. Okhlobystin, V. E. Zavodnik, and A. I. Lutsenko, Khim. Geterotsikl. Soedin., No. 3, 329 (1993).

  11. S. V. Zhuravlev and V. G. Kul'nevich, Khim. Geterotsikl. Soedin., No. 5, 597 (1983).

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Authors
  1. A. V. Butin
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  2. G. D. Krapivin
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  3. V. E. Zavodnik
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  4. V. G. Kul'nevich
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Additional information

For Communication 12, see [1].

Kubansk State Technological University, Krasnodar. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 648–653, May, 1996.

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Butin, A.V., Krapivin, G.D., Zavodnik, V.E. et al. Polyfuryl(aryl)alkanes and their derivatives. 13. Molecular structure of bis(5-methyl-2-furyl)(4-methoxyphenyl)methane and tris(5-methyl-2furyl)methane. Chem Heterocycl Compd 32, 555–559 (1996). https://doi.org/10.1007/BF01164784

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  • DOI: https://doi.org/10.1007/BF01164784

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