Abstract
Chloromethyl(dimethyl)pentafluorophenoxysilane (ClCH2SiMe2OC6F5) reacted with trimethylsilyl derivatives of N-methylacetamide, N-phenylacetamide, and N-methylbenzamide to form the corresponding (O—Si) chelates with a pentacoordinated silicon atom: N-[dimethyl(pentafluorophenoxy)silyl]methyl-N-methylacetamide, N-[dimethyl-(pentafluorophenoxy)silyl]methyl-N-phenylacetamide, and N-[dimethyl(pentafluorophenoxy)silyl]methyl-N-methylbenzamide. The structure of products was confirmed by multinuclear NMR spectroscopy, the mechanism of their formation was discussed.
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All results were obtained using the analytical equipment of the Baikal Center for Collective Use of the Siberian Branch of the Russian Academy of Sciences.
No human or animal subjects were used in this research.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 72, No. 9, pp. 2148–2153, September, 2023.
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Soldatenko, A.S., Lazareva, N.F. Chloromethyl(dimethyl)pentafluorophenoxysilane: synthesis and reactions with N-trimethylsilylcarboxamides. Russ Chem Bull 72, 2148–2153 (2023). https://doi.org/10.1007/s11172-023-4010-z
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DOI: https://doi.org/10.1007/s11172-023-4010-z