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(Chloromethyl)alkoxyhalogenosilanes in Reaction with N-Trimethylsilyl-N-methylacetamide

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Abstract

The reaction of N-trimethylsilyl-N-methylacetamide with polyfunctional silanes, namely methyl(chloromethyl)alkoxychlorosilanes and (chloromethyl)difluoro(isopropoxy)silane, was studied. Structure of the synthesized (O–Si)-chelates was studied by the quantum chemistry methods. Data on the apicophilicity of fluorine and chlorine atoms in these compounds were obtained.

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ACKNOWLEDGMENTS

The work was carried out using analytical equipment of the Baikal Center for Collective Use of the Siberian Branch of the Russian Academy of Sciences.

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Authors and Affiliations

  1. A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 664033, Irkutsk, Russia

    N. F. Lazareva, N. N. Chipanina, A. S. Soldatenko & L. P. Oznobikhina

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  1. N. F. Lazareva
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  2. N. N. Chipanina
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  3. A. S. Soldatenko
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  4. L. P. Oznobikhina
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Correspondence to N. F. Lazareva.

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To the 100th Anniversary of M.G. Voronkov

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Lazareva, N.F., Chipanina, N.N., Soldatenko, A.S. et al. (Chloromethyl)alkoxyhalogenosilanes in Reaction with N-Trimethylsilyl-N-methylacetamide. Russ J Gen Chem 91, 2403–2411 (2021). https://doi.org/10.1134/S1070363221120070

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  • DOI: https://doi.org/10.1134/S1070363221120070

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