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Synthesis and X-ray crystal structure of a five-coordinate d8 complex: [Pt((Me2NN)(PMe2)(PPh2))2Cl][Cl]

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Abstract

C36H50Cl2N6P4Pt·2 MeCN,2, triclinic P¯1,a=11.720(2),b=12.153(2),c=16.196(3),α=76.74(1),α=84.90(1),γ=88.13(1),Z=2,R=0.051,Rw=0.051. Interaction of Me2NN(PMe2)(PPh2),1, with Pt(COD)Cl2, COD=1,5 cyclooctadiene, in THF yields the title compound,2, in quantitative yield. Compound2 was characterized spectroscopically as well as via an X-ray diffraction study.

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Author notes

  1. S. G. Bott

    Present address: Department of Chemistry, University of North Texas, 76230, Denton, Texas

Authors and Affiliations

  1. Department of Chemistry, University of Texas at Arlington, 76019, Arlington, Texas

    C. J. Harlan & T. C. Wright

  2. Department of Chemistry, University of Alabama, 35487, Tuscaloosa, Alabama

    S. G. Bott & J. L. Atwood

Authors
  1. C. J. Harlan
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  2. T. C. Wright
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  3. S. G. Bott
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  4. J. L. Atwood
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Harlan, C.J., Wright, T.C., Bott, S.G. et al. Synthesis and X-ray crystal structure of a five-coordinate d8 complex: [Pt((Me2NN)(PMe2)(PPh2))2Cl][Cl]. Journal of Crystallographic and Spectroscopic Research 22, 71–75 (1992). https://doi.org/10.1007/BF01161366

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  • DOI: https://doi.org/10.1007/BF01161366

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