Skip to main content
SpringerLink
Log in

CRYSTAL STRUCTURES OF CoCl2·6H2O REACTION PRODUCTS WITH 2-METHYLPYRIDINE AND 2,6-DIMETHYLPYRIDINE

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

The reaction between CoCl2·6H2O and 2-methylpyridine (2-MePy) solutions in ethanol yields neutral [(2-MePy)2CoCl2] complex (1) isomorphic to previously described [(2-XPy)2CoCl2] (X = Cl, Br, I) forms. In the reaction with 2,6-dimethylpyridine (2,6-MePy), (2,6-MePyH)2[CoCl4] salt (2) forms instead of the heteroligand complex. The structures of 1 and 2 are determined by single crystal XRD.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2

Similar content being viewed by others

REFERENCES

  1. V. F. Duckworth and N. C. Stephenson. Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem., 1969, 25, 1795–1803.

    Article  CAS  Google Scholar 

  2. V. Kupčík and S. Ďurovič. Czechoslov. J. Phys., 1960, 10, 182–190.

    Article  Google Scholar 

  3. J. D. Dunitz. Acta Crystallogr., 1957, 10, 307–313.

    Article  CAS  Google Scholar 

  4. L. J. Admiraal and G. Gafner. Chem. Commun., 1968, 1221–1222.

    Article  Google Scholar 

  5. S. N. Herringer, M. M. Turnbull, C. P. Landee, and J. L. Wikaira. Dalton Trans., 2011, 40, 4242.

    Article  CAS  PubMed  Google Scholar 

  6. F. F. Awwadi, R. D. Willett, S. F. Haddad, and B. Twamley. Cryst. Growth Des., 2006, 6, 1833–1838.

    Article  CAS  Google Scholar 

  7. F. F. Awwadi, S. F. Haddad, M. M. Turnbull, C. P. Landee, and R. D. Willett. CrystEngComm, 2013, 15, 3111–3118.

    Article  CAS  Google Scholar 

  8. R. Puttreddy, C. von Essen, and K. Rissanen. Eur. J. Inorg. Chem., 2018, 2018, 2393–2398.

    Article  CAS  Google Scholar 

  9. R. Puttreddy, C. von Essen, A. Peuronen, M. Lahtinen, and K. Rissanen. CrystEngComm, 2018, 20, 1954–1959.

    Article  CAS  Google Scholar 

  10. A. Wang and U. Englert. Acta Crystallogr., Sect. C: Struct. Chem., 2017, 73, 803–809.

    Article  CAS  Google Scholar 

  11. G. R. Desiraju, P. S. Ho, L. Kloo, A. C. Legon, R. Marquardt, P. Metrangolo, P. Politzer, G. Resnati, and K. Rissanen. Pure Appl. Chem., 2013, 85, 1711–1713.

    Article  CAS  Google Scholar 

  12. G. Cavallo, P. Metrangolo, R. Milani, T. Pilati, A. Priimagi, G. Resnati, and G. Terraneo. Chem. Rev., 2016, 116, 2478–2601.

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  13. X. Ding, M. J. Tuikka, P. Hirva, V. Y. Kukushkin, A. S. Novikov, and M. Haukka. CrystEngComm, 2016, 18, 1987–1995.

    Article  CAS  Google Scholar 

  14. L. E. Zelenkov, D. M. Ivanov, M. S. Avdontceva, A. S. Novikov, and N. A. Bokach. Z. Krist. – Cryst. Mater., 2019, 234, 9–17.

    Article  CAS  Google Scholar 

  15. B. R. Mullaney, A. L. Thompson, and P. D. Beer. Angew. Chem., Int. Ed., 2014, 53, 11458–11462.

    Article  CAS  Google Scholar 

  16. V. V. Sivchik, A. I. Solomatina, Y.-T. Chen, A. J. Karttunen, S. P. Tunik, P.-T. Chou, and I. O. Koshevoy. Angew. Chem., Int. Ed., 2015, 54, 14057–14060.

    Article  CAS  Google Scholar 

  17. G. Mínguez Espallargas, A. J. Florence, J. van de Streek, and L. Brammer. CrystEngComm, 2011, 13, 4400.

    Article  CAS  Google Scholar 

  18. F. Zordan and L. Brammer. Cryst. Growth Des., 2006, 6, 1374–1379.

    Article  CAS  Google Scholar 

  19. F. Awwadi, R. D. Willett, and B. Twamley. Cryst. Growth Des., 2011, 11, 5316–5323.

    Article  CAS  Google Scholar 

  20. C. A. Krasinski, B. L. Solomon, F. F. Awwadi, C. P. Landee, M. M. Turnbull, and J. L. Wikaira. J. Coord. Chem., 2017, 70, 914–935.

    Article  CAS  Google Scholar 

  21. S. A. Adonin, M. A. Bondarenko, A. S. Novikov, and M. N. Sokolov. Crystals, 2020, 10, 289.

    Article  CAS  Google Scholar 

  22. J. Kansikas, M. Leskelä, G. Kenessey, P.-E. Werner, G. Liptay, J. Balzarini, B. Fransson, U. Ragnarsson, and G. W. Francis. Acta Chem. Scand., 1994, 48, 951–959.

    Article  CAS  Google Scholar 

  23. G. M. Sheldrick. Acta Crystallogr., Sect. C: Struct. Chem., 2015, 71, 3–8.

    Article  Google Scholar 

  24. J. R. Allan, C. L. Jones, and L. Sawyer. J. Inorg. Nucl. Chem., 1981, 43, 2707–2711.

    Article  CAS  Google Scholar 

  25. M. Laing and G. Carr. Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem., 1975, 31, 2683–2684.

    Article  Google Scholar 

  26. F. Jian, J. Zheng, P. Zhao, and Y. Li. J. Coord. Chem., 2008, 61, 705–714.

    Article  CAS  Google Scholar 

  27. R. A. Ahmadi, N. Safari, H. R. Khavasi, and S. Amani. J. Coord. Chem., 2011, 64, 2056–2065.

    Article  CAS  Google Scholar 

  28. A. Tadjarodi, K. Bijanzad, and B. Notash. Acta Crystallogr., Sect. E: Struct. Reports Online, 2010, 66, m1293–m1294.

    Article  CAS  Google Scholar 

  29. O. C. Sanchez Montilva, F. Movilla, M. G. Rodriguez, and F. Di Salvo. Acta Crystallogr., Sect. C: Struct. Chem., 2017, 73, 399–406.

    Article  CAS  Google Scholar 

  30. D. Wyrzykowski, E. Styczeń, Z. Warnke, and R. Kruszyński. Transit. Met. Chem., 2006, 31, 860–865.

    Article  CAS  Google Scholar 

  31. Z. Ma, S. Han, V. C. Kravtsov, and B. Moulton. Inorg. Chim. Acta, 2010, 363, 387–394.

    Article  CAS  Google Scholar 

  32. W. E. Marsh, W. E. Hatfield, and D. J. Hodgson. Inorg. Chem., 1982, 21, 2679–2684.

    Article  CAS  Google Scholar 

  33. M. C. Biagini, M. Ferrari, M. Lanfranchi, L. Marchiò, and M. A. Pellinghelli. J. Chem. Soc., Dalton Trans., 1999, 1575–1580.

    Article  Google Scholar 

  34. A. Krogul, J. Cedrowski, K. Wiktorska, W.P. Ozimiński, J. Skupińska, and G. Litwinienko. Dalton Trans., 2012, 41, 658–666.

    Article  CAS  PubMed  Google Scholar 

  35. J. A. Campbell, C. L. Raston, J. N. Varghese, and A. H. White. Aust. J. Chem., 1977, 30, 1947–1953.

    Article  CAS  Google Scholar 

  36. V. C. Gibson, C. Newton, C. Redshaw, G. A. Solan, A. J. P. White, and D. J. Williams. J. Chem. Soc., Dalton Trans., 2003, 3, 4612–4617.

    Article  Google Scholar 

  37. P. Saxena, N. Thirupathi, and M. Nethaji. Organometallics, 2014, 33, 3182–3197.

    Article  CAS  Google Scholar 

  38. P. Losier, D. C. MacQuarrie, and M. J. Zaworotko. J. Chem. Crystallogr., 1996, 26, 301–303.

    Article  CAS  Google Scholar 

  39. W. L. Darby, R. J. Butcher, and L. M. Vallarino. Inorg. Chim. Acta, 1992, 194, 113–117.

    Article  CAS  Google Scholar 

  40. L. Brammer, G. Mínguez Espallargas, and H. Adams. CrystEngComm, 2003, 5, 343–345.

    Article  Google Scholar 

  41. G. Mínguez Espallargas, F. Zordan, L. Arroyo Marín, H. Adams, K. Shankland, J. van de Streek, and L. Brammer. Chem. – Eur. J., 2009, 15, 7554–7568.

    Article  CAS  PubMed  Google Scholar 

  42. W. Li, S. L. Zheng, C. R. Zhu, Y. X. Tong, and X. M. Chen. Aust. J. Chem., 2002, 55, 561–563.

Download references

Funding

The work was supported by RFBR (Project No. 20-33-70010 “Stability”).

Author information

Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    M. A. Vershinin & S. A. Adonin

  2. Southern Ural State University, Chelyabinsk, Russia

    S. A. Adonin

Authors
  1. M. A. Vershinin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. A. Adonin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. A. Adonin.

Ethics declarations

The authors declare that they have no conflict of interests.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Vershinin, M.A., Adonin, S.A. CRYSTAL STRUCTURES OF CoCl2·6H2O REACTION PRODUCTS WITH 2-METHYLPYRIDINE AND 2,6-DIMETHYLPYRIDINE. J Struct Chem 62, 90–94 (2021). https://doi.org/10.1134/S0022476621010108

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476621010108

Keywords

Search

Navigation