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The crystal field theory for D2d symmetric complexes and the splitting of d-orbitals of Mo5+ in Mo[S2CN(C2H5)2]4I3

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Abstract

The energy order assignment of the d-orbitals of Mo5+ in Mo[S2CN(C2H5)2]4I3 given by Jasimet al. (1985) is restudied and corrected. It is indicated that, in general, the energy order of the d-orbitals of D2d symmetric complexes is depending on the bond angles and bond lengths of the ligands, thus there cannot be any universal energy order.

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References

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Authors and Affiliations

  1. Department of Physics, Chengdu University of Science and Technology, Chengdu, People's Republic of China

    Yang Jian-Hua

  2. Center of Theoretical Physics CCAST (World Laboratory) and Department of Physics, Sichuan University, Chengdu, People's Republic of China

    Zhou Kang-Wei

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  1. Yang Jian-Hua
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  2. Zhou Kang-Wei
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Jian-Hua, Y., Kang-Wei, Z. The crystal field theory for D2d symmetric complexes and the splitting of d-orbitals of Mo5+ in Mo[S2CN(C2H5)2]4I3 . Journal of Crystallographic and Spectroscopic Research 19, 929–931 (1989). https://doi.org/10.1007/BF01160874

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  • DOI: https://doi.org/10.1007/BF01160874

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