Abstract
Upper and lower bound estimates of the CuCl+ stability constants produced by various investigations have been quantitatively examined. Our analyses, including our own ultraviolet spectroscopic investigations, indicate that the CuCl+ stability constant in 1 molar HClO4 is β1=0.70±0.23. The CuCl+ molar absorptivity at a wavelength of 250 nm was determined as 1860 cm2-mol−1. Our analyses suggest the bound β ′≤0.371 for the formation constant of MgCl+ at one molar ionic strength.
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Byrne, R.H., van der Weijden, C.H., Kester, D.R. et al. Evaluation of the CuCl+ stability constant and molar absorptivity in aqueous media. J Solution Chem 12, 581–596 (1983). https://doi.org/10.1007/BF01150850
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DOI: https://doi.org/10.1007/BF01150850