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EPR investigation of complexes of copper(II) with o-aminomethylphenols

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    By EPR it was shown that complexes of copper(II) with o-aminomethylphenols contain a N2O2 coordination center tetrahedrally distorted in relation to the steric properties of the substituents at the N atom.

  2. 2.

    The reaction of complexes of 2∶1 ligand:copper composition with ethanol, water, and pyridine proceeds either by coordination of one or two solvents molecules or by a mechanism of outer-sphere coordination in relation to the steric properties of the substituents.

  3. 3.

    The structure-of the resulting complexes was explained by conformational mobility of the first coordination sphere.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch, Academy of Sciences of the USSR, USSR

    V. I. Morozov, I. S. Ryzhkina, L. A. Kudryavtseva, A. V. Il'yasov & B. E. Ivanov

Authors
  1. V. I. Morozov
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  2. I. S. Ryzhkina
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  3. L. A. Kudryavtseva
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  4. A. V. Il'yasov
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  5. B. E. Ivanov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1019–1023, May, 1985.

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Morozov, V.I., Ryzhkina, I.S., Kudryavtseva, L.A. et al. EPR investigation of complexes of copper(II) with o-aminomethylphenols. Russ Chem Bull 34, 927–931 (1985). https://doi.org/10.1007/BF01142777

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  • DOI: https://doi.org/10.1007/BF01142777

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