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Coordination compounds of hydrazine derivatives with transition metals. Part 24. Coordination chemistry of hydrazine-S-methyl carbodithioate schiff bases derived from β-dicarbonyl compounds

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Summary

The reactions of β-diketones and β-ketoaldehydes with hydrazine-S-methyl carbodithioate, hydth, have been studied in the absence and presence of metal(II) ions. A series of dimeric monoligand chelates [Ni(β-dikhydth-2H)]2 have been isolated. The reaction of these chelates with monodentate Lewis bases yields square planar [Ni(β-dikhydth2H)B] chelates. Bisligand chelates of benzoylacetone monohydrazones [M(Bzachydth-H)2] (M=Cu or Zn) have been also synthesized, as have a series of NiII and ZnII chelates of β-diketone bishydrazones of the type [M(β-dik(hydth)2-2H)].

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Authors and Affiliations

  1. Chemistry Department, Faculty of Science and University of Alexandria Research Center (UNARC), Alexandria University, Alexandria, Egypt

    Magdi F. Iskander, Laila El-Sayed, Ahmed El-Toukhy & Mohga Tawflk

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  1. Magdi F. Iskander
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  2. Laila El-Sayed
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  3. Ahmed El-Toukhy
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  4. Mohga Tawflk
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Iskander, M.F., El-Sayed, L., El-Toukhy, A. et al. Coordination compounds of hydrazine derivatives with transition metals. Part 24. Coordination chemistry of hydrazine-S-methyl carbodithioate schiff bases derived from β-dicarbonyl compounds. Transition Met Chem 7, 135–140 (1982). https://doi.org/10.1007/BF01035826

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  • DOI: https://doi.org/10.1007/BF01035826

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