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Complexes of borazine and its analogs with Lewis acids and bases

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Abstract

The author’s review summarizes the results of B3LYP/TZVP quantum chemical calculations of complexes of borazine, substituted borazines, polyborazines, alumazine, and boraphosphabenzene with Lewis acids and bases. The effects of the nature of the heterocycle, substituents, and the donor and acceptor properties of the molecules on the thermodynamic characteristics of complex formation are considered. The reactivity of the complexes of heterocycles in hydrogenation and electrophilic substitution reactions was studied.

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Authors and Affiliations

  1. Institute of Chemistry, Saint Petersburg State University, 7 Universitetskaya nab., 199034, St.-Petersburg, Russian Federation

    A. S. Lisovenko & A. Y. Timoshkin

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  1. A. S. Lisovenko
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  2. A. Y. Timoshkin
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Correspondence to A. Y. Timoshkin.

Additional information

Based on the materials of the XXVI International Chugaev Conference on Coordination Chemistry (October 6—10, 2014, Kazan, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2573—2585, November, 2015.

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Lisovenko, A.S., Timoshkin, A.Y. Complexes of borazine and its analogs with Lewis acids and bases. Russ Chem Bull 64, 2573–2585 (2015). https://doi.org/10.1007/s11172-015-1192-z

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  • DOI: https://doi.org/10.1007/s11172-015-1192-z

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