A rigorous theory of finite-size scaling at first-order phase transitions

Abstract

A large class of classical lattice models describing the coexistence of a finite number of stable states at low temperatures is considered. The dependence of the finite-volume magnetizationM _per(h, L) in cubes of sizeL ^dunder periodic boundary conditions on the external fieldh is analyzed. For the case where two phases coexist at the infinite-volume transition pointh _t , we prove that, independent of the details of the model, the finite-volume magnetization per lattice site behaves likeM _per(h _t )+M tanh[ML ^d(h−h_t)] withM _per(h) denoting the infinite-volume magnetization and M=1/2[M _per(h _t +0)−M _per(h _t −0)]. Introducing the finite-size transition pointh _m (L) as the point where the finite-volume susceptibility attains the maximum, we show that, in the case of asymmetric field-driven transitions, its shift ish _t −h _m (L)=O(L ^−2d), in contrast to claims in the literature. Starting from the obvious observation that the number of stable phases has a local maximum at the transition point, we propose a new way of determining the pointh _t from finite-size data with a shift that is exponentially small inL. Finally, the finite-size effects are discussed also in the case where more than two phases coexist.