Abstract
The Bjerrum association model has been extended to partial and apparent molar volumes. It was tested for electrolytes in water and in acetonitrile using literature or new (n-propylammonium bromide) data to cover systems having association constants between 0 and 105. The association constants and apparent distances of closest approach were obtained from conductivities. The volumes at low concentration can be fitted quantitatively to obtain by extrapolation the standard infinite dilution partial molar volume. Deviations at higher concentrations can be accounted for with a second virial coefficient.
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References
F. J. Millero, inActivity Coefficients in Electrolyte Solutions, R. M. Pytkowicz, ed., (CRC Press, Boca Raton, 1979), Vol. II, Chap. 2.
K. S. Pitzer, ibid,in, Vol. I, Chap. 7.
W. L. Masterton, H. Welles, J. H. Knox, and F. J. Millero,J. Solution Chem. 3, 91 (1974).
T. E. Burchfield and E. M. Woolley,J. Phys. Chem. 88, 2149 (1984).
E. M. Woolley and T. E. Burchfield,J. Phys. Chem. 88, 2155 (1984).
G. Perron, A. Hardy, J.-C. Justice, and J. E. Desnoyers,J. Solution Chem. 22, 1159 (1993).
N. Bjerrum, Kon. Danske Vidensk.Selskab 7 9 (1926).
R. M. Fuoss and F. Accascina,Electrolytic Conductance (Interscience, New York, 1959).
R. Fernández-Prini, inPhysical Chemistry of Organic Solvent Systems, A. K. Covington and T. Dickinson eds., (Plenum, New York, 1973), Chap. 5
J.-C. Justice,J. Solution Chem. 20, 1017 (1991).
J.-C. Justice, inComprehensive Treatise of Electrochemistry, Vol. 5, B. E. Conway, J O'M. Bockris, and E. Yeager, eds., (Plenum, New York, 1983), Chap. 3.
F. Quirion, D. Lambert, and G. Perron,Can. J. Chem. 70, 2745 (1992).
P. Picker, E. Tremblay, and C. Jolicoeur,J. Solution Chem. 3, 377 (1974).
A. C. Harkness and H. M. Daggett, Jr.,Can. J. Chem. 43, 1215 (1965).
D. F. Evans, C. Zawoyski, and R. L. Kay,J. Phys. Chem. 69, 3878 (1965).
CRC Handbook of Chemistry and Physics, 70th ed., R. C. Weast, ed., (CRC Press, Boca Raton, 1990), p. D-165.
A. D. Pethybridge and S. S. Taba,J. Chem. Soc., Faraday Trans. I 76, 368 (1980).
R. P. T. Tomkins, E. Andalaft, and G. J. Janz,Trans. Faraday Soc. 65, 1906 (1969).
J. K. Senne and B. Kratochvil,Analytical Chem. 43, 79 (1971).
R. Zana, G. Perron, and J. E. Desnoyers,J. Solution Chem. 8, 729 (1979).
H. L. Friedman,Ionic Solution Theory (Interscience, New York, 1962).
B. B. Owen, R. C. Miller, C. E. Milner, and H. L. Cogan,J. Phys. Chem. 65, 2065 (1961).
G. S. Kell,J. Chem. Eng. Data 12, 66 (1967).
F. J. Millero inWater and Aqueous Solutions: Structure, Thermodynamics, and Transport Processes, R. A. Horne, ed., (Wiley-Interscience, New York, 1972), Chap. 13.
J.-F. Côté, G. Perron, J. E. Desnoyers, and J.-M. St.-Arnaud,J. Solution Chem. (submitted).
I. Davidson, G. Perron, and J. E. Desnoyers,Can. J. Chem. 59, 2212 (1981).
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Côté, JF., Desnoyers, J.E. & Justice, JC. Application of the Bjerrum association model to volumes of electrolytes in water and acetonitrile. J Solution Chem 25, 113–134 (1996). https://doi.org/10.1007/BF00972684
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DOI: https://doi.org/10.1007/BF00972684