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Homo- and codimerization of bicyclo[2.2.1]-hepta-2,5-diene and its derivatives, catalyzed by rhodium complexes

  • Organic Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Mono- and binuclear rhodium complexes have been obtained which contain spiro(bicyclo[2.2.1]hepta-2,5-diene-7,1′-cyclopropane) as ligand.

  2. 2.

    A study has been carried out of the catalyzed (4+4) homodimerization and codimerization of spiro(bicyclo-[2.2.1]hepta-2,5-diene-7,1′-cyclopropane), leading to new octa- and nonacyclic hydrocarbons.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2299–2303, October, 1981.

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Zhemilev, U.M., Khusnutdinov, R.I., Muslimov, Z.S. et al. Homo- and codimerization of bicyclo[2.2.1]-hepta-2,5-diene and its derivatives, catalyzed by rhodium complexes. Russ Chem Bull 30, 1889–1892 (1981). https://doi.org/10.1007/BF00963416

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  • DOI: https://doi.org/10.1007/BF00963416

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