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Molecular structure of N,N′-bis(di-tert-butylphosphino)-N-trimethylsilylaminoiminophosphine

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    X-ray diffraction structural analysis established the structure and steric features of N,N′-bis(di-tert-butylphosphino)-N-trimethylsilylaminoiminophosphine, which is the first representative of dicoordinated phosphorus compounds with a

    bond system.

  2. 2.

    The unshared electron pair at the phosphorus atom bound to the “iminyl” nitrogen atom is virtually unconjugated with the P=N bond. Stabilization of the P=N bond is a consequence of the steric shielding by the bulky substituents.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow

    A. N. Chernega, M. Yu. Antipin, Yu. T. Struchkov, I. E. Bodeskul, E. O. Klebanskii & V. D. Romanenko

  2. Institute of Organic Chemistry, Academy of Sciences of the Ukrainian SSR, Kiev

    A. N. Chernega, M. Yu. Antipin, Yu. T. Struchkov, I. E. Bodeskul, E. O. Klebanskii & V. D. Romanenko

Authors
  1. A. N. Chernega
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  2. M. Yu. Antipin
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  3. Yu. T. Struchkov
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  4. I. E. Bodeskul
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  5. E. O. Klebanskii
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  6. V. D. Romanenko
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2236–2240, October, 1985.

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Chernega, A.N., Antipin, M.Y., Struchkov, Y.T. et al. Molecular structure of N,N′-bis(di-tert-butylphosphino)-N-trimethylsilylaminoiminophosphine. Russ Chem Bull 34, 2068–2071 (1985). https://doi.org/10.1007/BF00963235

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  • DOI: https://doi.org/10.1007/BF00963235

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