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Spectroscopic study of compounds with P-H bonds. 3. Di-n-propyl and diisopropyl phosphites

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Abstract

Data on the integral intensities of the Νv(P-H) bands of di-n-propyl phosphite and diisopropyl phosphite in different media have shown that in strong protonacceptor solvents the P-H group of the dialkyl phosphites examined is able to form weak hydrogen bonds. Beside this, association of liquid di-n-propyl and diisopropyl phosphites takes place by a dipole-dipole mechanism. Variations in the spectra as the medium, the temperature, and the phase are varied point to conformational nonuniformity in the di-n-propyl and diisopropyl phosphite molecules. The Ν(P-H) band is conformationally sensitive. In the crystal, a less polar, gauche, gauche form is achieved.

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Literature cited

  1. R. R. Shagidullin, L. Kh. Ashrafullina, and N. I. Monakhova, Dokl. Akad. Nauk SSSR,296, No. 3, 669 (1987).

    Google Scholar 

  2. R. R. Shagidullin, L. Kh. Ashrafullina, N. I. Monakhova, et al., Izv. Akad. Nauk SSSR, Ser. Khim., No. 6, 1282 (1989).

    Google Scholar 

  3. N. I. Monakhova, S. A. Katsyuba, L. Kh. Ashrafullina, et al., Zh. Prikl. Spectrosk.,51, No. 6, 944 (1989).

    Google Scholar 

  4. A. V. Iogansen, The Hydrogen Bond [in Russian], Nauka, Moscow (1981), p. 112.

    Google Scholar 

  5. O. A. Raevsky, Yu. A. Donskaja, F. G. Khalitov, et al., Phosphorus,5, 241 (1975).

    Google Scholar 

  6. C. D. Miller, R. C. Miller, and W. Rogers, J. Am. Chem. Soc.,80, No. 7, 1562 (1958).

    Google Scholar 

  7. Atlas of IR Spectra of Organophosphorus Compounds [in Russian], Nauka, Moscow (1984).

  8. Synthesis of Organophosphorus Molecules (Methodical Instructions for the Specialist Laboratory) [in Russian], Kazan State University, Kazan (1978).

  9. é. E. Nifant'ev, Chemistry of Organophosphorus Compounds [in Russian], Moscow State University, Moscow (1971), p. 51.

    Google Scholar 

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch, Academy of Sciences of the USSR, USSR

    R. R. Shagidullin, L. Kh. Ashrafullina, N. I. Monakhova & S. A. Terent'eva

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  1. R. R. Shagidullin
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  2. L. Kh. Ashrafullina
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  3. N. I. Monakhova
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  4. S. A. Terent'eva
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 564–567, March, 1990.

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Shagidullin, R.R., Ashrafullina, L.K., Monakhova, N.I. et al. Spectroscopic study of compounds with P-H bonds. 3. Di-n-propyl and diisopropyl phosphites. Russ Chem Bull 39, 489–491 (1990). https://doi.org/10.1007/BF00959567

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  • DOI: https://doi.org/10.1007/BF00959567

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