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Structure of pyridine and quinoline vinyl ethers according to data from1H and13C NMR spectra and quantum-chemical calculations

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The vinyl ethers of pyridine and quinoline exist preferentially in the nonplanar Strans conformation.

  2. 2.

    In the vinyl esters of pyridine and quinoline the p-Π conjugation is concurrent in nature and depends on the position of the vinyloxy group in the heterocycle.

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR

    A. V. Afonin, V. K. Voronov, M. A. Andriankov & D. K. Danovich

Authors
  1. A. V. Afonin
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  2. V. K. Voronov
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  3. M. A. Andriankov
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  4. D. K. Danovich
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Additional information

Translated from Izvestiya Akademii Nauk SSSR. Seriya Khimicheskaya, No. 2, pp. 317–323, February, 1987.

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Afonin, A.V., Voronov, V.K., Andriankov, M.A. et al. Structure of pyridine and quinoline vinyl ethers according to data from1H and13C NMR spectra and quantum-chemical calculations. Russ Chem Bull 36, 279–284 (1987). https://doi.org/10.1007/BF00959363

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  • DOI: https://doi.org/10.1007/BF00959363

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